Synthesis of a novel magnetic Caragana korshinskii biochar/Mg–Al layered double hydroxide composite and its strong adsorption of phosphate in aqueous solutions

Phosphate pollution of aquatic ecosystems is of great concern and requires the development of high-performance materials for effective pollution treatment. To realize efficient phosphate removal from aqueous solution, an easily separable magnetic (Fe(3)O(4)) Caragana korshinskii biochar/Mg–Al layered double hydroxide composite (denoted as FCB/MAC) was synthesized via two-step electro-assisted modification for the first time. Subsequently, the physical and chemical properties of FCB/MAC were characterized. Furthermore, the sorption mechanism for phosphate removal was investigated in detail. The results indicated that Fe(3)O(4) and the Mg–Al layered double hydroxide were successfully embedded in the biochar matrix. Moreover, FCB/MAC exhibited a high phosphate adsorption capacity and excellent magnetic properties for easy recovery. The maximum phosphate sorption capacity of FCB/MAC was 252.88 mg g(−1), which is much higher than the capacities of most magnetic phosphate adsorbents. In addition, the adsorption kinetics and isotherms indicated that phosphate adsorption by FCB/MAC was controlled by the pseudo-second-order kinetic model and the Langmuir–Freundlich isotherm model. The phosphate adsorption mechanism involves anion exchange, electrostatic attraction, and ligand exchange. After five adsorption–desorption cycles, the phosphate adsorption capacity of FCB/MAC was 25.71 mg g(−1) with 51.43% removal efficiency and high recyclability. Thus, the composite prepared in this study is a promising adsorbent for phosphate removal from aqueous solution, and this work provides an excellent reference for constructing novel biochar-based phosphate adsorbents.