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Solvent-free incorporation of CO(2) into 2-oxazolidinones: a review
This review is an attempt to give an overview on the recent advances and developments in the synthesis of 2-oxazolidinone frameworks through carbon dioxide (CO(2)) fixation reactions under solvent-free conditions. The cycloaddition of CO(2) to aziridine derivatives is discussed first. This is follow...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9065275/ https://www.ncbi.nlm.nih.gov/pubmed/35519371 http://dx.doi.org/10.1039/c9ra00551j |
Sumario: | This review is an attempt to give an overview on the recent advances and developments in the synthesis of 2-oxazolidinone frameworks through carbon dioxide (CO(2)) fixation reactions under solvent-free conditions. The cycloaddition of CO(2) to aziridine derivatives is discussed first. This is followed by carboxylative cyclization of N-propargylamines with CO(2) and three-component coupling of epoxides, amines, and CO(2). Finally, cycloaddition of CO(2) to propargylic alcohols and amines will be covered at the end of the review. The literature has been surveyed up until the end of 2018. |
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