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La(2)O(3)-coated Li(2)ZnTi(3)O(8)@C as a high performance anode for lithium-ion batteries

Li(2)ZnTi(3)O(8)C@La(2)O(3) (LZTO@C@La(2)O(3)) coated with composite protective layers is successfully fabricated via a facile solid-state route. The co-coating strategy greatly improves the electrochemical performance of LZTO. 89.8%, 77.2% and 76.7% of the discharge specific capacities for the 2nd...

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Detalles Bibliográficos
Autores principales: Meng, Zhaohui, Wang, Suhong, Wang, Hongwei, Wang, Lijuan, Wang, Song
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9065805/
https://www.ncbi.nlm.nih.gov/pubmed/35515568
http://dx.doi.org/10.1039/c9ra03846a
Descripción
Sumario:Li(2)ZnTi(3)O(8)C@La(2)O(3) (LZTO@C@La(2)O(3)) coated with composite protective layers is successfully fabricated via a facile solid-state route. The co-coating strategy greatly improves the electrochemical performance of LZTO. 89.8%, 77.2% and 76.7% of the discharge specific capacities for the 2nd cycle can be retained at the 200th cycle at 1, 2 and 3 A g(−1), respectively. At 4 and 5 A g(−1), 174.3 and 166.1 are still retained for the 100th cycle, respectively. Even at a high temperature of 55 °C, LZTO@C@La(2)O(3) still has good cycling performance. The excellent electrochemical performance is due to the stable surface structure between LZTO and the electrolyte, a good conductive network, small particle size, and large specific surface area as well as pore volume.