Enantioselective Michael reaction of anthrone catalyzed by chiral tetraoxacalix[2]arene[2]triazine derivatives

A highly enantioselective Michael addition reaction of anthrone with nitroalkenes by chiral tetraoxacalix[2]arene[2]triazine catalysts was investigated as a novel topic. The stereoselective conversion progressed smoothly by employing 10 mol% of the catalyst and afforded the corresponding Michael add...

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Autor principal: Genc, Hayriye Nevin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9065986/
https://www.ncbi.nlm.nih.gov/pubmed/35515554
http://dx.doi.org/10.1039/c9ra03029h
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author Genc, Hayriye Nevin
author_facet Genc, Hayriye Nevin
author_sort Genc, Hayriye Nevin
collection PubMed
description A highly enantioselective Michael addition reaction of anthrone with nitroalkenes by chiral tetraoxacalix[2]arene[2]triazine catalysts was investigated as a novel topic. The stereoselective conversion progressed smoothly by employing 10 mol% of the catalyst and afforded the corresponding Michael adducts with acceptable to high enantioselectivities (up to 97% ee) and very high yields (up to 96%).
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spelling pubmed-90659862022-05-04 Enantioselective Michael reaction of anthrone catalyzed by chiral tetraoxacalix[2]arene[2]triazine derivatives Genc, Hayriye Nevin RSC Adv Chemistry A highly enantioselective Michael addition reaction of anthrone with nitroalkenes by chiral tetraoxacalix[2]arene[2]triazine catalysts was investigated as a novel topic. The stereoselective conversion progressed smoothly by employing 10 mol% of the catalyst and afforded the corresponding Michael adducts with acceptable to high enantioselectivities (up to 97% ee) and very high yields (up to 96%). The Royal Society of Chemistry 2019-07-05 /pmc/articles/PMC9065986/ /pubmed/35515554 http://dx.doi.org/10.1039/c9ra03029h Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Genc, Hayriye Nevin
Enantioselective Michael reaction of anthrone catalyzed by chiral tetraoxacalix[2]arene[2]triazine derivatives
title Enantioselective Michael reaction of anthrone catalyzed by chiral tetraoxacalix[2]arene[2]triazine derivatives
title_full Enantioselective Michael reaction of anthrone catalyzed by chiral tetraoxacalix[2]arene[2]triazine derivatives
title_fullStr Enantioselective Michael reaction of anthrone catalyzed by chiral tetraoxacalix[2]arene[2]triazine derivatives
title_full_unstemmed Enantioselective Michael reaction of anthrone catalyzed by chiral tetraoxacalix[2]arene[2]triazine derivatives
title_short Enantioselective Michael reaction of anthrone catalyzed by chiral tetraoxacalix[2]arene[2]triazine derivatives
title_sort enantioselective michael reaction of anthrone catalyzed by chiral tetraoxacalix[2]arene[2]triazine derivatives
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9065986/
https://www.ncbi.nlm.nih.gov/pubmed/35515554
http://dx.doi.org/10.1039/c9ra03029h
work_keys_str_mv AT genchayriyenevin enantioselectivemichaelreactionofanthronecatalyzedbychiraltetraoxacalix2arene2triazinederivatives

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