Layered metal–organic framework based on tetracyanonickelate as a cathode material for in situ Li-ion storage

Prussian blue analogs (PBAs) formed with hexacyanide linkers have been studied for decades. The framework crystal structure of PBAs mainly benefits from the six-fold coordinated cyano functional groups. In this study, in-plane tetracyanonickelate was utilized to engineer an organic linker and design a family of four-fold coordinated PBAs (FF-PBAs; Fe(2+)Ni(CN)(4), MnNi(CN)(4), Fe(3+)Ni(CN)(4), CuNi(CN)(4), CoNi(CN)(4), ZnNi(CN)(4), and NiNi(CN)(4)), which showed an interesting two-dimensional (2D) crystal structure. It was found that these FF-PBAs could be utilized as cathode materials of Li-ion batteries, and the Ni/Fe(2+) system exhibited superior electrochemical properties compared to the others with a capacity of 137.9 mA h g(−1) at a current density of 100 mA g(−1). Furthermore, after a 5000-cycle long-term repeated charge/discharge measurement, the Ni/Fe(2+) system displayed a capacity of 60.3 mA h g(−1) with a coulombic efficiency of 98.8% at a current density of 1000 mA g(−1). In addition, the capacity of 86.1% was preserved at 1000 mA g(−1) as compared with that at 100 mA g(−1), implying a good rate capability. These potential capacities can be ascribed to an in situ reduction of Li(+) in the interlayer of Ni/Fe(2+) instead of the formation of other compounds with the host material according to ex situ XRD characterization. These specially designed FF-PBAs are expected to inspire new concepts in electrochemistry and other applications requiring 2D materials.