Copper-catalyzed synthesis of phenol and diaryl ether derivatives via hydroxylation of diaryliodoniums

A copper-catalysed hydroxylation of diaryliodoniums to generate phenols and diaryl ethers is reported. This method allows the synthesis of diversely functionalized phenols under mild reaction conditions without the need for a strong inorganic base or an expensive noble-metal catalyst. Significantly,...

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Detalles Bibliográficos
Autores principales: Ye, Lianbao, Han, Chao, Shi, Peiqi, Gao, Wei, Mei, Wenjie
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9066359/
https://www.ncbi.nlm.nih.gov/pubmed/35521308
http://dx.doi.org/10.1039/c9ra04282b
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author Ye, Lianbao
Han, Chao
Shi, Peiqi
Gao, Wei
Mei, Wenjie
author_facet Ye, Lianbao
Han, Chao
Shi, Peiqi
Gao, Wei
Mei, Wenjie
author_sort Ye, Lianbao
collection PubMed
description A copper-catalysed hydroxylation of diaryliodoniums to generate phenols and diaryl ethers is reported. This method allows the synthesis of diversely functionalized phenols under mild reaction conditions without the need for a strong inorganic base or an expensive noble-metal catalyst. Significantly, convenient application of diaryliodoniums is demonstrated in the preparation of diaryl ethers in a one-pot operation.
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spelling pubmed-90663592022-05-04 Copper-catalyzed synthesis of phenol and diaryl ether derivatives via hydroxylation of diaryliodoniums Ye, Lianbao Han, Chao Shi, Peiqi Gao, Wei Mei, Wenjie RSC Adv Chemistry A copper-catalysed hydroxylation of diaryliodoniums to generate phenols and diaryl ethers is reported. This method allows the synthesis of diversely functionalized phenols under mild reaction conditions without the need for a strong inorganic base or an expensive noble-metal catalyst. Significantly, convenient application of diaryliodoniums is demonstrated in the preparation of diaryl ethers in a one-pot operation. The Royal Society of Chemistry 2019-07-10 /pmc/articles/PMC9066359/ /pubmed/35521308 http://dx.doi.org/10.1039/c9ra04282b Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Ye, Lianbao
Han, Chao
Shi, Peiqi
Gao, Wei
Mei, Wenjie
Copper-catalyzed synthesis of phenol and diaryl ether derivatives via hydroxylation of diaryliodoniums
title Copper-catalyzed synthesis of phenol and diaryl ether derivatives via hydroxylation of diaryliodoniums
title_full Copper-catalyzed synthesis of phenol and diaryl ether derivatives via hydroxylation of diaryliodoniums
title_fullStr Copper-catalyzed synthesis of phenol and diaryl ether derivatives via hydroxylation of diaryliodoniums
title_full_unstemmed Copper-catalyzed synthesis of phenol and diaryl ether derivatives via hydroxylation of diaryliodoniums
title_short Copper-catalyzed synthesis of phenol and diaryl ether derivatives via hydroxylation of diaryliodoniums
title_sort copper-catalyzed synthesis of phenol and diaryl ether derivatives via hydroxylation of diaryliodoniums
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9066359/
https://www.ncbi.nlm.nih.gov/pubmed/35521308
http://dx.doi.org/10.1039/c9ra04282b
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