Cargando…
Porous organic polymer with in situ generated palladium nanoparticles as a phase-transfer catalyst for Sonogashira cross-coupling reaction in water
A new Pd nanoparticle loaded and imidazolium-ionic liquid decorated organic polymer of Pd@PTC-POP was readily fabricated via a Pd(PPh(3))(4) catalysed in situ one-pot Suzuki cross-coupling reaction between imidazolium attached dibromobenzene and 1,3,5-tri(4-pinacholatoborolanephenyl)benzene. Besides...
Autores principales: | , , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2019
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9066429/ https://www.ncbi.nlm.nih.gov/pubmed/35518897 http://dx.doi.org/10.1039/c9ra04103f |
_version_ | 1784699801682575360 |
---|---|
author | Dong, Ying Chen, Yun-Qi Jv, Jing-Jing Li, Yue Li, Wen-Han Dong, Yu-Bin |
author_facet | Dong, Ying Chen, Yun-Qi Jv, Jing-Jing Li, Yue Li, Wen-Han Dong, Yu-Bin |
author_sort | Dong, Ying |
collection | PubMed |
description | A new Pd nanoparticle loaded and imidazolium-ionic liquid decorated organic polymer of Pd@PTC-POP was readily fabricated via a Pd(PPh(3))(4) catalysed in situ one-pot Suzuki cross-coupling reaction between imidazolium attached dibromobenzene and 1,3,5-tri(4-pinacholatoborolanephenyl)benzene. Besides the high thermal and chemical stability, the obtained Pd@PTC-POP can be used as a highly active and reusable phase-transfer solid catalyst to promote the Sonogashira coupling reaction in water. The obtained results indicate that the Pd@PTC-POP herein could create a versatile family of solid phase transfer catalysts for promoting a broad scope of reactions carried out in water. |
format | Online Article Text |
id | pubmed-9066429 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2019 |
publisher | The Royal Society of Chemistry |
record_format | MEDLINE/PubMed |
spelling | pubmed-90664292022-05-04 Porous organic polymer with in situ generated palladium nanoparticles as a phase-transfer catalyst for Sonogashira cross-coupling reaction in water Dong, Ying Chen, Yun-Qi Jv, Jing-Jing Li, Yue Li, Wen-Han Dong, Yu-Bin RSC Adv Chemistry A new Pd nanoparticle loaded and imidazolium-ionic liquid decorated organic polymer of Pd@PTC-POP was readily fabricated via a Pd(PPh(3))(4) catalysed in situ one-pot Suzuki cross-coupling reaction between imidazolium attached dibromobenzene and 1,3,5-tri(4-pinacholatoborolanephenyl)benzene. Besides the high thermal and chemical stability, the obtained Pd@PTC-POP can be used as a highly active and reusable phase-transfer solid catalyst to promote the Sonogashira coupling reaction in water. The obtained results indicate that the Pd@PTC-POP herein could create a versatile family of solid phase transfer catalysts for promoting a broad scope of reactions carried out in water. The Royal Society of Chemistry 2019-07-12 /pmc/articles/PMC9066429/ /pubmed/35518897 http://dx.doi.org/10.1039/c9ra04103f Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/ |
spellingShingle | Chemistry Dong, Ying Chen, Yun-Qi Jv, Jing-Jing Li, Yue Li, Wen-Han Dong, Yu-Bin Porous organic polymer with in situ generated palladium nanoparticles as a phase-transfer catalyst for Sonogashira cross-coupling reaction in water |
title | Porous organic polymer with in situ generated palladium nanoparticles as a phase-transfer catalyst for Sonogashira cross-coupling reaction in water |
title_full | Porous organic polymer with in situ generated palladium nanoparticles as a phase-transfer catalyst for Sonogashira cross-coupling reaction in water |
title_fullStr | Porous organic polymer with in situ generated palladium nanoparticles as a phase-transfer catalyst for Sonogashira cross-coupling reaction in water |
title_full_unstemmed | Porous organic polymer with in situ generated palladium nanoparticles as a phase-transfer catalyst for Sonogashira cross-coupling reaction in water |
title_short | Porous organic polymer with in situ generated palladium nanoparticles as a phase-transfer catalyst for Sonogashira cross-coupling reaction in water |
title_sort | porous organic polymer with in situ generated palladium nanoparticles as a phase-transfer catalyst for sonogashira cross-coupling reaction in water |
topic | Chemistry |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9066429/ https://www.ncbi.nlm.nih.gov/pubmed/35518897 http://dx.doi.org/10.1039/c9ra04103f |
work_keys_str_mv | AT dongying porousorganicpolymerwithinsitugeneratedpalladiumnanoparticlesasaphasetransfercatalystforsonogashiracrosscouplingreactioninwater AT chenyunqi porousorganicpolymerwithinsitugeneratedpalladiumnanoparticlesasaphasetransfercatalystforsonogashiracrosscouplingreactioninwater AT jvjingjing porousorganicpolymerwithinsitugeneratedpalladiumnanoparticlesasaphasetransfercatalystforsonogashiracrosscouplingreactioninwater AT liyue porousorganicpolymerwithinsitugeneratedpalladiumnanoparticlesasaphasetransfercatalystforsonogashiracrosscouplingreactioninwater AT liwenhan porousorganicpolymerwithinsitugeneratedpalladiumnanoparticlesasaphasetransfercatalystforsonogashiracrosscouplingreactioninwater AT dongyubin porousorganicpolymerwithinsitugeneratedpalladiumnanoparticlesasaphasetransfercatalystforsonogashiracrosscouplingreactioninwater |