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Porous organic polymer with in situ generated palladium nanoparticles as a phase-transfer catalyst for Sonogashira cross-coupling reaction in water

A new Pd nanoparticle loaded and imidazolium-ionic liquid decorated organic polymer of Pd@PTC-POP was readily fabricated via a Pd(PPh(3))(4) catalysed in situ one-pot Suzuki cross-coupling reaction between imidazolium attached dibromobenzene and 1,3,5-tri(4-pinacholatoborolanephenyl)benzene. Besides...

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Detalles Bibliográficos
Autores principales: Dong, Ying, Chen, Yun-Qi, Jv, Jing-Jing, Li, Yue, Li, Wen-Han, Dong, Yu-Bin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9066429/
https://www.ncbi.nlm.nih.gov/pubmed/35518897
http://dx.doi.org/10.1039/c9ra04103f
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author Dong, Ying
Chen, Yun-Qi
Jv, Jing-Jing
Li, Yue
Li, Wen-Han
Dong, Yu-Bin
author_facet Dong, Ying
Chen, Yun-Qi
Jv, Jing-Jing
Li, Yue
Li, Wen-Han
Dong, Yu-Bin
author_sort Dong, Ying
collection PubMed
description A new Pd nanoparticle loaded and imidazolium-ionic liquid decorated organic polymer of Pd@PTC-POP was readily fabricated via a Pd(PPh(3))(4) catalysed in situ one-pot Suzuki cross-coupling reaction between imidazolium attached dibromobenzene and 1,3,5-tri(4-pinacholatoborolanephenyl)benzene. Besides the high thermal and chemical stability, the obtained Pd@PTC-POP can be used as a highly active and reusable phase-transfer solid catalyst to promote the Sonogashira coupling reaction in water. The obtained results indicate that the Pd@PTC-POP herein could create a versatile family of solid phase transfer catalysts for promoting a broad scope of reactions carried out in water.
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spelling pubmed-90664292022-05-04 Porous organic polymer with in situ generated palladium nanoparticles as a phase-transfer catalyst for Sonogashira cross-coupling reaction in water Dong, Ying Chen, Yun-Qi Jv, Jing-Jing Li, Yue Li, Wen-Han Dong, Yu-Bin RSC Adv Chemistry A new Pd nanoparticle loaded and imidazolium-ionic liquid decorated organic polymer of Pd@PTC-POP was readily fabricated via a Pd(PPh(3))(4) catalysed in situ one-pot Suzuki cross-coupling reaction between imidazolium attached dibromobenzene and 1,3,5-tri(4-pinacholatoborolanephenyl)benzene. Besides the high thermal and chemical stability, the obtained Pd@PTC-POP can be used as a highly active and reusable phase-transfer solid catalyst to promote the Sonogashira coupling reaction in water. The obtained results indicate that the Pd@PTC-POP herein could create a versatile family of solid phase transfer catalysts for promoting a broad scope of reactions carried out in water. The Royal Society of Chemistry 2019-07-12 /pmc/articles/PMC9066429/ /pubmed/35518897 http://dx.doi.org/10.1039/c9ra04103f Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/
spellingShingle Chemistry
Dong, Ying
Chen, Yun-Qi
Jv, Jing-Jing
Li, Yue
Li, Wen-Han
Dong, Yu-Bin
Porous organic polymer with in situ generated palladium nanoparticles as a phase-transfer catalyst for Sonogashira cross-coupling reaction in water
title Porous organic polymer with in situ generated palladium nanoparticles as a phase-transfer catalyst for Sonogashira cross-coupling reaction in water
title_full Porous organic polymer with in situ generated palladium nanoparticles as a phase-transfer catalyst for Sonogashira cross-coupling reaction in water
title_fullStr Porous organic polymer with in situ generated palladium nanoparticles as a phase-transfer catalyst for Sonogashira cross-coupling reaction in water
title_full_unstemmed Porous organic polymer with in situ generated palladium nanoparticles as a phase-transfer catalyst for Sonogashira cross-coupling reaction in water
title_short Porous organic polymer with in situ generated palladium nanoparticles as a phase-transfer catalyst for Sonogashira cross-coupling reaction in water
title_sort porous organic polymer with in situ generated palladium nanoparticles as a phase-transfer catalyst for sonogashira cross-coupling reaction in water
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9066429/
https://www.ncbi.nlm.nih.gov/pubmed/35518897
http://dx.doi.org/10.1039/c9ra04103f
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