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Prospective application of phosphorylated carbon nanofibers with a high adsorption capacity for the sequestration of uranium from ground water
In this study carbon nanofibers (CNF) were phosphorylated by using ortho-phosphoric acid and applied for adsorptive remediation of uranium from water. The phosphorylated carbon nanofibers (PCNF) showed 96% removal of uranium as compared to 79% by CNF. The adsorption data from batch adsorption studie...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9066443/ https://www.ncbi.nlm.nih.gov/pubmed/35520136 http://dx.doi.org/10.1039/d2ra02031a |
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author | Dhanya, V. Arunraj, Balasubramanian Rajesh, N. |
author_facet | Dhanya, V. Arunraj, Balasubramanian Rajesh, N. |
author_sort | Dhanya, V. |
collection | PubMed |
description | In this study carbon nanofibers (CNF) were phosphorylated by using ortho-phosphoric acid and applied for adsorptive remediation of uranium from water. The phosphorylated carbon nanofibers (PCNF) showed 96% removal of uranium as compared to 79% by CNF. The adsorption data from batch adsorption studies fitted well with the Langmuir model and a maximum adsorption capacity of 512.8 mg g(−1) was obtained at pH 6.0 while the adsorption followed pseudo second order kinetics. A detailed characterisation of the adsorbent has been carried out using various analytical and spectroscopic tools. The application of the adsorbent to ground water samples exhibited promising results even in the presence of other interfering cations and anions which is imperative considering the toxic effects of uranium in ground water. |
format | Online Article Text |
id | pubmed-9066443 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2022 |
publisher | The Royal Society of Chemistry |
record_format | MEDLINE/PubMed |
spelling | pubmed-90664432022-05-04 Prospective application of phosphorylated carbon nanofibers with a high adsorption capacity for the sequestration of uranium from ground water Dhanya, V. Arunraj, Balasubramanian Rajesh, N. RSC Adv Chemistry In this study carbon nanofibers (CNF) were phosphorylated by using ortho-phosphoric acid and applied for adsorptive remediation of uranium from water. The phosphorylated carbon nanofibers (PCNF) showed 96% removal of uranium as compared to 79% by CNF. The adsorption data from batch adsorption studies fitted well with the Langmuir model and a maximum adsorption capacity of 512.8 mg g(−1) was obtained at pH 6.0 while the adsorption followed pseudo second order kinetics. A detailed characterisation of the adsorbent has been carried out using various analytical and spectroscopic tools. The application of the adsorbent to ground water samples exhibited promising results even in the presence of other interfering cations and anions which is imperative considering the toxic effects of uranium in ground water. The Royal Society of Chemistry 2022-05-04 /pmc/articles/PMC9066443/ /pubmed/35520136 http://dx.doi.org/10.1039/d2ra02031a Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/ |
spellingShingle | Chemistry Dhanya, V. Arunraj, Balasubramanian Rajesh, N. Prospective application of phosphorylated carbon nanofibers with a high adsorption capacity for the sequestration of uranium from ground water |
title | Prospective application of phosphorylated carbon nanofibers with a high adsorption capacity for the sequestration of uranium from ground water |
title_full | Prospective application of phosphorylated carbon nanofibers with a high adsorption capacity for the sequestration of uranium from ground water |
title_fullStr | Prospective application of phosphorylated carbon nanofibers with a high adsorption capacity for the sequestration of uranium from ground water |
title_full_unstemmed | Prospective application of phosphorylated carbon nanofibers with a high adsorption capacity for the sequestration of uranium from ground water |
title_short | Prospective application of phosphorylated carbon nanofibers with a high adsorption capacity for the sequestration of uranium from ground water |
title_sort | prospective application of phosphorylated carbon nanofibers with a high adsorption capacity for the sequestration of uranium from ground water |
topic | Chemistry |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9066443/ https://www.ncbi.nlm.nih.gov/pubmed/35520136 http://dx.doi.org/10.1039/d2ra02031a |
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