Low-cost and environmentally friendly synthesis of an Al(3+) and Mn(4+) co-doped Li(4)Ti(5)O(12) composite with carbon quantum dots as an anode for lithium-ion batteries

To increase the specific capacity and conductivity of lithium titanate (LTO), low-cost and environmentally friendly carbon quantum dots (CQDs) were used to composite with Al(3+) and Mn(4+) co-doped Li(4)Ti(5)O(12) (LTO-Al/Mn) to improve its electrical properties. The Al(3+) and Mn(4+) were successfu...

Descripción completa

Detalles Bibliográficos
Autores principales: Nan, Hui, Zhang, Yiming, Wei, Haomin, Chen, Huiyuan, Xue, Caihong, Yang, Guijun, Zou, Shuai, Wang, Gang, Lin, Hong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9066617/
https://www.ncbi.nlm.nih.gov/pubmed/35518851
http://dx.doi.org/10.1039/c9ra03897c
_version_ 1784699831592157184
author Nan, Hui
Zhang, Yiming
Wei, Haomin
Chen, Huiyuan
Xue, Caihong
Yang, Guijun
Zou, Shuai
Wang, Gang
Lin, Hong
author_facet Nan, Hui
Zhang, Yiming
Wei, Haomin
Chen, Huiyuan
Xue, Caihong
Yang, Guijun
Zou, Shuai
Wang, Gang
Lin, Hong
author_sort Nan, Hui
collection PubMed
description To increase the specific capacity and conductivity of lithium titanate (LTO), low-cost and environmentally friendly carbon quantum dots (CQDs) were used to composite with Al(3+) and Mn(4+) co-doped Li(4)Ti(5)O(12) (LTO-Al/Mn) to improve its electrical properties. The Al(3+) and Mn(4+) were successfully substituted for Ti located at (16d) sites in the LTO and the CQDs formed a composite with LTO-Al/Mn. The specific capacity of the first cycle at 0.1C increased to 296.5 mA h g(−1), and the impedance decreased to 16.8 Ω. The specific capacity maintained 236.0 mA h g(−1) after 100 cycles.
format Online
Article
Text
id pubmed-9066617
institution National Center for Biotechnology Information
language English
publishDate 2019
publisher The Royal Society of Chemistry
record_format MEDLINE/PubMed
spelling pubmed-90666172022-05-04 Low-cost and environmentally friendly synthesis of an Al(3+) and Mn(4+) co-doped Li(4)Ti(5)O(12) composite with carbon quantum dots as an anode for lithium-ion batteries Nan, Hui Zhang, Yiming Wei, Haomin Chen, Huiyuan Xue, Caihong Yang, Guijun Zou, Shuai Wang, Gang Lin, Hong RSC Adv Chemistry To increase the specific capacity and conductivity of lithium titanate (LTO), low-cost and environmentally friendly carbon quantum dots (CQDs) were used to composite with Al(3+) and Mn(4+) co-doped Li(4)Ti(5)O(12) (LTO-Al/Mn) to improve its electrical properties. The Al(3+) and Mn(4+) were successfully substituted for Ti located at (16d) sites in the LTO and the CQDs formed a composite with LTO-Al/Mn. The specific capacity of the first cycle at 0.1C increased to 296.5 mA h g(−1), and the impedance decreased to 16.8 Ω. The specific capacity maintained 236.0 mA h g(−1) after 100 cycles. The Royal Society of Chemistry 2019-07-16 /pmc/articles/PMC9066617/ /pubmed/35518851 http://dx.doi.org/10.1039/c9ra03897c Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Nan, Hui
Zhang, Yiming
Wei, Haomin
Chen, Huiyuan
Xue, Caihong
Yang, Guijun
Zou, Shuai
Wang, Gang
Lin, Hong
Low-cost and environmentally friendly synthesis of an Al(3+) and Mn(4+) co-doped Li(4)Ti(5)O(12) composite with carbon quantum dots as an anode for lithium-ion batteries
title Low-cost and environmentally friendly synthesis of an Al(3+) and Mn(4+) co-doped Li(4)Ti(5)O(12) composite with carbon quantum dots as an anode for lithium-ion batteries
title_full Low-cost and environmentally friendly synthesis of an Al(3+) and Mn(4+) co-doped Li(4)Ti(5)O(12) composite with carbon quantum dots as an anode for lithium-ion batteries
title_fullStr Low-cost and environmentally friendly synthesis of an Al(3+) and Mn(4+) co-doped Li(4)Ti(5)O(12) composite with carbon quantum dots as an anode for lithium-ion batteries
title_full_unstemmed Low-cost and environmentally friendly synthesis of an Al(3+) and Mn(4+) co-doped Li(4)Ti(5)O(12) composite with carbon quantum dots as an anode for lithium-ion batteries
title_short Low-cost and environmentally friendly synthesis of an Al(3+) and Mn(4+) co-doped Li(4)Ti(5)O(12) composite with carbon quantum dots as an anode for lithium-ion batteries
title_sort low-cost and environmentally friendly synthesis of an al(3+) and mn(4+) co-doped li(4)ti(5)o(12) composite with carbon quantum dots as an anode for lithium-ion batteries
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9066617/
https://www.ncbi.nlm.nih.gov/pubmed/35518851
http://dx.doi.org/10.1039/c9ra03897c
work_keys_str_mv AT nanhui lowcostandenvironmentallyfriendlysynthesisofanal3andmn4codopedli4ti5o12compositewithcarbonquantumdotsasananodeforlithiumionbatteries
AT zhangyiming lowcostandenvironmentallyfriendlysynthesisofanal3andmn4codopedli4ti5o12compositewithcarbonquantumdotsasananodeforlithiumionbatteries
AT weihaomin lowcostandenvironmentallyfriendlysynthesisofanal3andmn4codopedli4ti5o12compositewithcarbonquantumdotsasananodeforlithiumionbatteries
AT chenhuiyuan lowcostandenvironmentallyfriendlysynthesisofanal3andmn4codopedli4ti5o12compositewithcarbonquantumdotsasananodeforlithiumionbatteries
AT xuecaihong lowcostandenvironmentallyfriendlysynthesisofanal3andmn4codopedli4ti5o12compositewithcarbonquantumdotsasananodeforlithiumionbatteries
AT yangguijun lowcostandenvironmentallyfriendlysynthesisofanal3andmn4codopedli4ti5o12compositewithcarbonquantumdotsasananodeforlithiumionbatteries
AT zoushuai lowcostandenvironmentallyfriendlysynthesisofanal3andmn4codopedli4ti5o12compositewithcarbonquantumdotsasananodeforlithiumionbatteries
AT wanggang lowcostandenvironmentallyfriendlysynthesisofanal3andmn4codopedli4ti5o12compositewithcarbonquantumdotsasananodeforlithiumionbatteries
AT linhong lowcostandenvironmentallyfriendlysynthesisofanal3andmn4codopedli4ti5o12compositewithcarbonquantumdotsasananodeforlithiumionbatteries

Ejemplares similares