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Solubility of hydrocarbon oils in alcohols (≤C(6)) and synthesis of difusel carbonate for degreasing
The empirical solubility of hydrocarbon fluids, polyalphaolefin (PAO) and mineral oil, in thirteen small molecular weight alcohols (C(1)–C(6)) was determined. Butanols, pentanols, and 1-hexanol could dissolve up to PAO-10 and mineral oil. tert-Pentanol and 1-hexanol could also dissolve high-viscosit...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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The Royal Society of Chemistry
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9067106/ https://www.ncbi.nlm.nih.gov/pubmed/35514517 http://dx.doi.org/10.1039/c9ra04220b |
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author | Davis, Matthew C. Fedick, Patrick W. Lupton, David V. Ostrom, Gregory S. Quintana, Roxanne Woodroffe, Josanne-Dee |
author_facet | Davis, Matthew C. Fedick, Patrick W. Lupton, David V. Ostrom, Gregory S. Quintana, Roxanne Woodroffe, Josanne-Dee |
author_sort | Davis, Matthew C. |
collection | PubMed |
description | The empirical solubility of hydrocarbon fluids, polyalphaolefin (PAO) and mineral oil, in thirteen small molecular weight alcohols (C(1)–C(6)) was determined. Butanols, pentanols, and 1-hexanol could dissolve up to PAO-10 and mineral oil. tert-Pentanol and 1-hexanol could also dissolve high-viscosity PAO-150. The dialkyl carbonate of fusel oil (DFC) was synthesized from dimethyl carbonate in 69% yield. DFC had excellent non-polar solubility and could dissolve PAO-150 and several common industrial lubricants. The flash point of DFC was 93 °C, more than twice that of isoamyl alcohol. DFC had net heating value of 30.47 MJ kg(−1), nearly double that of dimethyl carbonate. However, its derived cetane number of 22.8 indicates DFC could not be used directly as diesel fuel. |
format | Online Article Text |
id | pubmed-9067106 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2019 |
publisher | The Royal Society of Chemistry |
record_format | MEDLINE/PubMed |
spelling | pubmed-90671062022-05-04 Solubility of hydrocarbon oils in alcohols (≤C(6)) and synthesis of difusel carbonate for degreasing Davis, Matthew C. Fedick, Patrick W. Lupton, David V. Ostrom, Gregory S. Quintana, Roxanne Woodroffe, Josanne-Dee RSC Adv Chemistry The empirical solubility of hydrocarbon fluids, polyalphaolefin (PAO) and mineral oil, in thirteen small molecular weight alcohols (C(1)–C(6)) was determined. Butanols, pentanols, and 1-hexanol could dissolve up to PAO-10 and mineral oil. tert-Pentanol and 1-hexanol could also dissolve high-viscosity PAO-150. The dialkyl carbonate of fusel oil (DFC) was synthesized from dimethyl carbonate in 69% yield. DFC had excellent non-polar solubility and could dissolve PAO-150 and several common industrial lubricants. The flash point of DFC was 93 °C, more than twice that of isoamyl alcohol. DFC had net heating value of 30.47 MJ kg(−1), nearly double that of dimethyl carbonate. However, its derived cetane number of 22.8 indicates DFC could not be used directly as diesel fuel. The Royal Society of Chemistry 2019-07-24 /pmc/articles/PMC9067106/ /pubmed/35514517 http://dx.doi.org/10.1039/c9ra04220b Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/ |
spellingShingle | Chemistry Davis, Matthew C. Fedick, Patrick W. Lupton, David V. Ostrom, Gregory S. Quintana, Roxanne Woodroffe, Josanne-Dee Solubility of hydrocarbon oils in alcohols (≤C(6)) and synthesis of difusel carbonate for degreasing |
title | Solubility of hydrocarbon oils in alcohols (≤C(6)) and synthesis of difusel carbonate for degreasing |
title_full | Solubility of hydrocarbon oils in alcohols (≤C(6)) and synthesis of difusel carbonate for degreasing |
title_fullStr | Solubility of hydrocarbon oils in alcohols (≤C(6)) and synthesis of difusel carbonate for degreasing |
title_full_unstemmed | Solubility of hydrocarbon oils in alcohols (≤C(6)) and synthesis of difusel carbonate for degreasing |
title_short | Solubility of hydrocarbon oils in alcohols (≤C(6)) and synthesis of difusel carbonate for degreasing |
title_sort | solubility of hydrocarbon oils in alcohols (≤c(6)) and synthesis of difusel carbonate for degreasing |
topic | Chemistry |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9067106/ https://www.ncbi.nlm.nih.gov/pubmed/35514517 http://dx.doi.org/10.1039/c9ra04220b |
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