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Oxidative dehalogenation of trichlorophenol catalyzed by a promiscuous artificial heme-enzyme

The miniaturized metalloenzyme Fe(iii)-mimochrome VI*a (Fe(iii)-MC6*a) acts as an excellent biocatalyst in the H(2)O(2)-mediated oxidative dehalogenation of the well-known pesticide and biocide 2,4,6-trichlorophenol (TCP). The artificial enzyme can oxidize TCP with a catalytic efficiency (k(cat)/K(T...

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Detalles Bibliográficos
Autores principales:	Zambrano, Gerardo, Sekretareva, Alina, D'Alonzo, Daniele, Leone, Linda, Pavone, Vincenzo, Lombardi, Angela, Nastri, Flavia
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2022
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9067433/ https://www.ncbi.nlm.nih.gov/pubmed/35527726 http://dx.doi.org/10.1039/d2ra00811d

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