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Molecular rotational conformation controls the rate of singlet fission and triplet decay in pentacene dimers

Three pentacene dimers have been synthesized to investigate the effect of molecular rotation and rotational conformations on singlet fission (SF). In all three dimers, the pentacene units are linked by a 1,4-diethynylphenylene spacer that provides almost unimpeded rotational freedom between the pent...

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Detalles Bibliográficos
Autores principales: Ringström, Rasmus, Edhborg, Fredrik, Schroeder, Zachary W., Chen, Lan, Ferguson, Michael J., Tykwinski, Rik R., Albinsson, Bo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9067590/
https://www.ncbi.nlm.nih.gov/pubmed/35655894
http://dx.doi.org/10.1039/d1sc06285a