Geometrical influence on the non-biomimetic heterolytic splitting of H(2) by bio-inspired [FeFe]-hydrogenase complexes: a rare example of inverted frustrated Lewis pair based reactivity

Despite the high levels of interest in the synthesis of bio-inspired [FeFe]-hydrogenase complexes, H(2) oxidation, which is one specific aspect of hydrogenase enzymatic activity, is not observed for most reported complexes. To attempt H–H bond cleavage, two disubstituted diiron dithiolate complexes...

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Detalles Bibliográficos
Autores principales: Chatelain, Lucile, Breton, Jean-Baptiste, Arrigoni, Federica, Schollhammer, Philippe, Zampella, Giuseppe
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9067592/
https://www.ncbi.nlm.nih.gov/pubmed/35655865
http://dx.doi.org/10.1039/d1sc06975f

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9067592/
https://www.ncbi.nlm.nih.gov/pubmed/35655865
http://dx.doi.org/10.1039/d1sc06975f

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