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Geometrical influence on the non-biomimetic heterolytic splitting of H(2) by bio-inspired [FeFe]-hydrogenase complexes: a rare example of inverted frustrated Lewis pair based reactivity
Despite the high levels of interest in the synthesis of bio-inspired [FeFe]-hydrogenase complexes, H(2) oxidation, which is one specific aspect of hydrogenase enzymatic activity, is not observed for most reported complexes. To attempt H–H bond cleavage, two disubstituted diiron dithiolate complexes...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9067592/ https://www.ncbi.nlm.nih.gov/pubmed/35655865 http://dx.doi.org/10.1039/d1sc06975f |