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Isolable fluorinated triphenylmethyl cation salts of [HCB(11)Cl(11)](−): demonstration of remarkable hydride affinity
Significantly fluorinated triarylmethyl cations have long attracted attention as potentially accessible highly reactive carbocations, but their isolation in a convenient form has proved elusive. We show that abstraction of chloride with a cationic silylium reagent leads to the facile formation of di...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9067617/ https://www.ncbi.nlm.nih.gov/pubmed/35655874 http://dx.doi.org/10.1039/d1sc05936j |