Doubly stereoconvergent construction of vicinal all-carbon quaternary and tertiary stereocenters by Cu/Mg-catalyzed propargylic substitution

The construction of vicinal, congested stereocenters with high selectivities is of general utility in chemistry. To build two such stereocenters in one step from readily available starting materials is very desirable, but remains challenging. We report here a doubly stereoconvergent, Cu/Mg-catalyzed...

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Detalles Bibliográficos
Autores principales: Pu, Xiang, Dang, Qiu-Di, Yang, Lei, Zhang, Xia, Niu, Dawen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9068607/
https://www.ncbi.nlm.nih.gov/pubmed/35508476
http://dx.doi.org/10.1038/s41467-022-29986-y

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9068607/
https://www.ncbi.nlm.nih.gov/pubmed/35508476
http://dx.doi.org/10.1038/s41467-022-29986-y

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