Cargando…
Hydrogen bonds-triggered differential extraction efficiencies for bifenthrin by three polymeric ionic liquids with varying anions based on FT-IR spectroscopy
Herein, we fabricated three imidazolium-based polymeric ionic liquids (PILs) with different anions (P[VEIM]BF(4), P[VEIM]PF(6) and P[VEIM]Br), and analyzed their differential extraction efficiencies for bifenthrin through H-bonding induced effects. Three PILs all presented an irregular block structu...
Autores principales: | , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2022
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9069304/ https://www.ncbi.nlm.nih.gov/pubmed/35530395 http://dx.doi.org/10.1039/d2ra01371a |
Sumario: | Herein, we fabricated three imidazolium-based polymeric ionic liquids (PILs) with different anions (P[VEIM]BF(4), P[VEIM]PF(6) and P[VEIM]Br), and analyzed their differential extraction efficiencies for bifenthrin through H-bonding induced effects. Three PILs all presented an irregular block structure with rough surface and lower specific-surface area (SSA, 11.2–18.7 m(2) g(−1)) than carbon-based nanomaterials. They formed hydrogen bonds with free-water molecules in the lattice of PILs, including C(2,4,5)–H⋯O–H, Br⋯H–O–H⋯Br, O–H⋯Br, C(2,4,5)–H⋯F–P, P–F⋯H–O–H⋯F–P, C(2,4,5)–H⋯F–B and B–F⋯H–O–H⋯F–B. After extraction, the O–H stretching-vibration peak was prominently intensified, whereas the C–H bond varied slightly concomitant with reduced B–F and P–F vibration. Theoretically, the C–H vibration should become more intense in the C(4,5)–H⋯H(2)O and C(2)–H⋯H(2)O bonds after extraction in contrast to before extraction. These contrary spectral changes demonstrated that the hydrogen bonds between cations in the PILs and free-water molecules were broken after extraction, yielding the H-bonding occurrence between bifenthrin and H–O–H in the lattice. As a time indicator for the free-water binding and releasing process, the highest slope for the plot of I(t)/I(0) against time implied that the shortest time was required for P[VEIM]PF(6) to reach an adsorption equilibrium. Overall, the strong hydrophobicity, small SSA and electrostatic-repulsion force for P[VEIM]PF(6) are all not conducive to its efficient adsorption. Beyond our anticipation, P[VEIM]PF(6) provided the highest extraction recovery for bifenthrin up to 92.4% among three PILs. Therefore, these data lead us to posit that the above high efficiency results from the strongest H-bonding effect between P[VEIM]PF(6) and bifenthrin. These findings promote our deep understanding of PILs-triggered differential efficiency through a H-bonding induced effect. |
---|