tBuOK-triggered bond formation reactions

Recently, inexpensive and readily available tBuOK has seen widespread use in transition-metal-free reactions. Herein, we report the use of tBuOK for S–S, S–Se, N[double bond, length as m-dash]N and C[double bond, length as m-dash]N bond formations, which significantly extends the scope of tBuOK in c...

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Detalles Bibliográficos
Autores principales: Xu, Yulong, Shi, Xiaonan, Wu, Lipeng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9069448/
https://www.ncbi.nlm.nih.gov/pubmed/35530574
http://dx.doi.org/10.1039/c9ra04242c
Descripción
Sumario:Recently, inexpensive and readily available tBuOK has seen widespread use in transition-metal-free reactions. Herein, we report the use of tBuOK for S–S, S–Se, N[double bond, length as m-dash]N and C[double bond, length as m-dash]N bond formations, which significantly extends the scope of tBuOK in chemical synthesis. Compared with traditional methods, we have realized mild and general methods for disulfide, azobenzenes imine etc. synthesis.

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