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Synthesis, crystal structure and photophysical properties of chlorido[(E)-3-hydroxy-2-methyl-6-(quinolin-8-yldiazenyl)phenolato]copper(II) monohydrate
The reaction between copper(II) chloride dihydrate and the (E)-2-methyl-4-(quinolin-8-yldiazenyl)benzene-1,3-diol ligand in acetonitrile leads to the formation of the title compound, [Cu(C(16)H(12)N(3)O(2))Cl]·H(2)O. The ligand is deprotonated and coordinates with three donor atoms (tridentate) to...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2022
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9069510/ https://www.ncbi.nlm.nih.gov/pubmed/35547789 http://dx.doi.org/10.1107/S2056989022003437 |
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author | Kachi-Terajima, Chihiro Hagiwara, Seiya |
author_facet | Kachi-Terajima, Chihiro Hagiwara, Seiya |
author_sort | Kachi-Terajima, Chihiro |
collection | PubMed |
description | The reaction between copper(II) chloride dihydrate and the (E)-2-methyl-4-(quinolin-8-yldiazenyl)benzene-1,3-diol ligand in acetonitrile leads to the formation of the title compound, [Cu(C(16)H(12)N(3)O(2))Cl]·H(2)O. The ligand is deprotonated and coordinates with three donor atoms (tridentate) to the Cu(II) ion. Individual molecules of the Cu(II) complex are connected by chloride bridges, forming a one-dimensional coordination polymer. No photoisomerization to the cis isomer of the azo ligand was observed upon irradiation with UV light. |
format | Online Article Text |
id | pubmed-9069510 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2022 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-90695102022-05-10 Synthesis, crystal structure and photophysical properties of chlorido[(E)-3-hydroxy-2-methyl-6-(quinolin-8-yldiazenyl)phenolato]copper(II) monohydrate Kachi-Terajima, Chihiro Hagiwara, Seiya Acta Crystallogr E Crystallogr Commun Research Communications The reaction between copper(II) chloride dihydrate and the (E)-2-methyl-4-(quinolin-8-yldiazenyl)benzene-1,3-diol ligand in acetonitrile leads to the formation of the title compound, [Cu(C(16)H(12)N(3)O(2))Cl]·H(2)O. The ligand is deprotonated and coordinates with three donor atoms (tridentate) to the Cu(II) ion. Individual molecules of the Cu(II) complex are connected by chloride bridges, forming a one-dimensional coordination polymer. No photoisomerization to the cis isomer of the azo ligand was observed upon irradiation with UV light. International Union of Crystallography 2022-04-05 /pmc/articles/PMC9069510/ /pubmed/35547789 http://dx.doi.org/10.1107/S2056989022003437 Text en © Kachi-Terajima and Hagiwara 2022 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Research Communications Kachi-Terajima, Chihiro Hagiwara, Seiya Synthesis, crystal structure and photophysical properties of chlorido[(E)-3-hydroxy-2-methyl-6-(quinolin-8-yldiazenyl)phenolato]copper(II) monohydrate |
title | Synthesis, crystal structure and photophysical properties of chlorido[(E)-3-hydroxy-2-methyl-6-(quinolin-8-yldiazenyl)phenolato]copper(II) monohydrate |
title_full | Synthesis, crystal structure and photophysical properties of chlorido[(E)-3-hydroxy-2-methyl-6-(quinolin-8-yldiazenyl)phenolato]copper(II) monohydrate |
title_fullStr | Synthesis, crystal structure and photophysical properties of chlorido[(E)-3-hydroxy-2-methyl-6-(quinolin-8-yldiazenyl)phenolato]copper(II) monohydrate |
title_full_unstemmed | Synthesis, crystal structure and photophysical properties of chlorido[(E)-3-hydroxy-2-methyl-6-(quinolin-8-yldiazenyl)phenolato]copper(II) monohydrate |
title_short | Synthesis, crystal structure and photophysical properties of chlorido[(E)-3-hydroxy-2-methyl-6-(quinolin-8-yldiazenyl)phenolato]copper(II) monohydrate |
title_sort | synthesis, crystal structure and photophysical properties of chlorido[(e)-3-hydroxy-2-methyl-6-(quinolin-8-yldiazenyl)phenolato]copper(ii) monohydrate |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9069510/ https://www.ncbi.nlm.nih.gov/pubmed/35547789 http://dx.doi.org/10.1107/S2056989022003437 |
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