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Electrocatalytic oxidation of water by the immobilized [Cu(II)(l-ala)(Phen)(H(2)O)](+) complex on a self-assembled NCS(−) modified gold electrode
Copper(ii) complex [Cu(II)(l-ala)(Phen)(H(2)O)](+) (l-ala = l-phenylalanine, phen = phenanthroline) was immobilized over a self-assembled NCS(−) modified gold electrode for the electrocatalytic oxidation of water. This surface anchored molecular complex can catalyze water oxidation reaction at a rem...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9069537/ https://www.ncbi.nlm.nih.gov/pubmed/35530588 http://dx.doi.org/10.1039/c9ra02547b |
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author | Mahanta, Abhinandan Barman, Koushik Jasimuddin, Sk |
author_facet | Mahanta, Abhinandan Barman, Koushik Jasimuddin, Sk |
author_sort | Mahanta, Abhinandan |
collection | PubMed |
description | Copper(ii) complex [Cu(II)(l-ala)(Phen)(H(2)O)](+) (l-ala = l-phenylalanine, phen = phenanthroline) was immobilized over a self-assembled NCS(−) modified gold electrode for the electrocatalytic oxidation of water. This surface anchored molecular complex can catalyze water oxidation reaction at a remarkably low overpotential of 327 mV with a current density of 0.5 mA cm(−2) at neutral pH. |
format | Online Article Text |
id | pubmed-9069537 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2019 |
publisher | The Royal Society of Chemistry |
record_format | MEDLINE/PubMed |
spelling | pubmed-90695372022-05-05 Electrocatalytic oxidation of water by the immobilized [Cu(II)(l-ala)(Phen)(H(2)O)](+) complex on a self-assembled NCS(−) modified gold electrode Mahanta, Abhinandan Barman, Koushik Jasimuddin, Sk RSC Adv Chemistry Copper(ii) complex [Cu(II)(l-ala)(Phen)(H(2)O)](+) (l-ala = l-phenylalanine, phen = phenanthroline) was immobilized over a self-assembled NCS(−) modified gold electrode for the electrocatalytic oxidation of water. This surface anchored molecular complex can catalyze water oxidation reaction at a remarkably low overpotential of 327 mV with a current density of 0.5 mA cm(−2) at neutral pH. The Royal Society of Chemistry 2019-08-01 /pmc/articles/PMC9069537/ /pubmed/35530588 http://dx.doi.org/10.1039/c9ra02547b Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/ |
spellingShingle | Chemistry Mahanta, Abhinandan Barman, Koushik Jasimuddin, Sk Electrocatalytic oxidation of water by the immobilized [Cu(II)(l-ala)(Phen)(H(2)O)](+) complex on a self-assembled NCS(−) modified gold electrode |
title | Electrocatalytic oxidation of water by the immobilized [Cu(II)(l-ala)(Phen)(H(2)O)](+) complex on a self-assembled NCS(−) modified gold electrode |
title_full | Electrocatalytic oxidation of water by the immobilized [Cu(II)(l-ala)(Phen)(H(2)O)](+) complex on a self-assembled NCS(−) modified gold electrode |
title_fullStr | Electrocatalytic oxidation of water by the immobilized [Cu(II)(l-ala)(Phen)(H(2)O)](+) complex on a self-assembled NCS(−) modified gold electrode |
title_full_unstemmed | Electrocatalytic oxidation of water by the immobilized [Cu(II)(l-ala)(Phen)(H(2)O)](+) complex on a self-assembled NCS(−) modified gold electrode |
title_short | Electrocatalytic oxidation of water by the immobilized [Cu(II)(l-ala)(Phen)(H(2)O)](+) complex on a self-assembled NCS(−) modified gold electrode |
title_sort | electrocatalytic oxidation of water by the immobilized [cu(ii)(l-ala)(phen)(h(2)o)](+) complex on a self-assembled ncs(−) modified gold electrode |
topic | Chemistry |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9069537/ https://www.ncbi.nlm.nih.gov/pubmed/35530588 http://dx.doi.org/10.1039/c9ra02547b |
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