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CIDNP as a tool to unveil the reaction mechanism: interaction of mixed phosphonium–iodonium ylide with p-methoxyphenylacetylene

In situ acquisition of the reaction between benzoyl phosphonium–iodonium ylide and p-methoxyphenylacetylene in an NMR spectrometer reveals the CIDNP effect in (31)P and (1)H NMR spectra of major products, substituted furan (emission) and phosphonium salt (enhanced absorption). The mechanism of produ...

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Detalles Bibliográficos
Autores principales: Levina, Irina I., Tarasov, Valery F., Podrugina, Tatyana A., Nekipelova, Tatiana D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9070124/
https://www.ncbi.nlm.nih.gov/pubmed/35531024
http://dx.doi.org/10.1039/c9ra05697a

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