Cargando…

Catalyst-free chemoselective α-sulfenylation/β-thiolation for α,β-unsaturated carbonyl compounds

A novel, efficient, catalyst-free and product-controllable strategy has been developed for the chemoselective α-sulfenylation/β-thiolation of α,β-unsaturated carbonyl compounds. An aromatic sulfur group could be chemoselectively introduced at α- or β-position of carbonyls with different sulfur reage...

Descripción completa

Detalles Bibliográficos
Autores principales:	Huang, Xi, Li, Juan, Li, Xiang, Wang, Jiayi, Peng, Yanqing, Song, Gonghua
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2019
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9070314/ https://www.ncbi.nlm.nih.gov/pubmed/35531013 http://dx.doi.org/10.1039/c9ra05708k

Ejemplares similares

Copper(i) pyrimidine-2-thiolate cluster-based polymers as bifunctional visible-light-photocatalysts for chemoselective transfer hydrogenation of α,β-unsaturated carbonyls
por: Zhang, Meng Juan, et al.
Publicado: (2021)

Assessing Methodologies to Synthesize α‐Sulfenylated Carbonyl Compounds by Green Chemistry Metrics
por: Margalef, Jèssica, et al.
Publicado: (2020)

Thermodynamics Evaluation of Selective Hydride Reduction for α,β-Unsaturated Carbonyl Compounds
por: Chen, Bao-Long, et al.
Publicado: (2023)

Regioselective radical α-borylation of α,β-unsaturated carbonyl compounds for direct synthesis of α-borylcarbonyl molecules
por: Ren, Shi-Chao, et al.
Publicado: (2019)

Copper Foam as Active Catalysts for the Borylation of α, β-Unsaturated Compounds
por: Zheng, Kewang, et al.
Publicado: (2022)

K(2)S(2)O(8)-promoted C–Se bond formation to construct α-phenylseleno carbonyl compounds and α,β-unsaturated carbonyl compounds
por: Yang, Xue-Yan, et al.
Publicado: (2020)

Chromophore Activation of α,β‐Unsaturated Carbonyl Compounds and Its Application to Enantioselective Photochemical Reactions
por: Brenninger, Christoph, et al.
Publicado: (2018)

Antileishmanial and antitrypanosomal activity of symmetrical dibenzyl-substituted α,β-unsaturated carbonyl-based compounds
por: Alkhaldi, Abdulsalam AM, et al.
Publicado: (2019)

AgOTf-catalyzed one-pot reactions of 2-alkynylbenzaldoximes with α,β-unsaturated carbonyl compounds
por: Ding, Qiuping, et al.
Publicado: (2013)

A borane-mediated palladium-catalyzed reductive allylic alkylation of α,β-unsaturated carbonyl compounds
por: Trost, Barry M., et al.
Publicado: (2020)

Manganese(I)-Catalyzed Asymmetric Hydrophosphination of α,β-Unsaturated Carbonyl Derivatives
por: Postolache, Roxana, et al.
Publicado: (2023)

Preparation of Modified Chitosan Microsphere-Supported Copper Catalysts for the Borylation of α,β-Unsaturated Compounds
por: Wang, Wei, et al.
Publicado: (2019)

Multicomponent synthesis and photophysical study of novel α,β-unsaturated carbonyl depsipeptides and peptoids
por: González, Ricelia, et al.
Publicado: (2023)

Chemoselective γ‐Oxidation of β,γ‐Unsaturated Amides with TEMPO
por: Heindl, Sebastian, et al.
Publicado: (2021)

Immunosuppressive Effects of Natural α,β-Unsaturated Carbonyl-Based Compounds, and Their Analogs and Derivatives, on Immune Cells: A Review
por: Arshad, Laiba, et al.
Publicado: (2017)

Electroreductive coupling of 2-acylbenzoates with α,β-unsaturated carbonyl compounds: density functional theory study on product selectivity
por: Kise, Naoki, et al.
Publicado: (2022)

Chemoselective α,β‐Dehydrogenation of Saturated Amides
por: Teskey, Christopher J., et al.
Publicado: (2018)

K(2)CO(3)-Promoted oxy-Michael Addition/Cyclization of α,β-Unsaturated Carbonyl Compounds with Naphthols: Synthesis of Naphthopyrans
por: Li, Shan-Shan, et al.
Publicado: (2023)

Chemoselective and metal-free reduction of α,β-unsaturated ketones by in situ produced benzeneselenol from O-(tert-butyl) Se-phenyl selenocarbonate
por: Temperini, Andrea, et al.
Publicado: (2020)

A practical method for the aziridination of α,β-unsaturated carbonyl compounds with a simple carbamate utilizing sodium hypochlorite pentahydrate
por: Umeda, Takehiro, et al.
Publicado: (2021)

Metal-Free Vinyl C–H Sulfenylation/Alkyl Thiolation of Ketene Dithioacetals for the Synthesis of Polythiolated Alkenes
por: Deng, Leiling, et al.
Publicado: (2018)

Catalytic Asymmetric Peroxidation of α,β-Unsaturated Nitroalkenes by a Bifunctional Organic Catalyst
por: Lu, Xiaojie, et al.
Publicado: (2014)

Palladium-catalyzed chemoselective direct α-arylation of carbonyl compounds with chloroaryl triflates at the C–Cl site
por: Chen, Zicong, et al.
Publicado: (2022)

Tetrabutylammonium Iodide–Promoted Thiolation of Oxindoles Using Sulfonyl Chlorides as Sulfenylation Reagents
por: Zhao, Xia, et al.
Publicado: (2017)

Deciphering Methylation Effects on S(2)(ππ*) Internal Conversion in the Simplest Linear α,β-Unsaturated Carbonyl
por: Chakraborty, Pratip, et al.
Publicado: (2023)

Aryloxide‐Facilitated Catalyst Turnover in Enantioselective α,β‐Unsaturated Acyl Ammonium Catalysis
por: Matviitsuk, Anastassia, et al.
Publicado: (2017)

Intertwining Olefin Thianthrenation with Kornblum/Ganem Oxidations: Ene‐type Oxidation to Furnish α,β‐Unsaturated Carbonyls
por: Angyal, Péter, et al.
Publicado: (2022)

Chemoselective and one-pot synthesis of novel coumarin-based cyclopenta[c]pyrans via base-mediated reaction of α,β-unsaturated coumarins and β-ketodinitriles
por: Farajpour, Behnaz, et al.
Publicado: (2022)

Visible-light-induced, Ir-catalyzed reactions of N-methyl-N-((trimethylsilyl)methyl)aniline with cyclic α,β-unsaturated carbonyl compounds
por: Lenhart, Dominik, et al.
Publicado: (2014)

Hydroxy-directed iridium-catalyzed enantioselective formal β-C(sp(2))–H allylic alkylation of α,β-unsaturated carbonyls
por: Mitra, Sankash, et al.
Publicado: (2022)

Studies of adsorption of α,β-unsaturated carbonyl compounds on heterogeneous Au/CeO(2), Au/TiO(2) and Au/SiO(2) catalysts during reduction by hydrogen
por: Zielinski, Maciej, et al.
Publicado: (2022)

Efficient synthesis of β’-amino-α,β-unsaturated ketones
por: Abrunhosa-Thomas, Isabelle, et al.
Publicado: (2013)

Correction: Chemoselective and one-pot synthesis of novel coumarin-based cyclopenta[c]pyrans via base-mediated reaction of α,β-unsaturated coumarins and β-ketodinitriles
por: Farajpour, Behnaz, et al.
Publicado: (2022)

Palladium‐Catalyzed Cascade Carbonylation to α,β‐Unsaturated Piperidones via Selective Cleavage of Carbon–Carbon Triple Bonds
por: Ge, Yao, et al.
Publicado: (2021)

Fe(OTf)(3)-catalysed Friedel–Crafts reaction of benzenoid arenes with α,β-unsaturated carbonyl compounds: easy access to 1,1-diarylalkanes
por: Bhattacharya, Aditya, et al.
Publicado: (2017)

Metal-Free Regiodivergent Addition of Carbon Nucleophiles to α,β-Unsaturated Electrophiles
por: Spitz, Cédric, et al.
Publicado: (2017)

Efficient 1,4-addition of α-substituted fluoro(phenylsulfonyl)methane derivatives to α,β-unsaturated compounds
por: Prakash, G K Surya, et al.
Publicado: (2008)

Magnesium-catalyzed hydrosilylation of α,β-unsaturated esters
por: Lampland, Nicole L., et al.
Publicado: (2015)

Thionation of Some α,β-Unsaturated Steroidal Ketones
por: Krstić, Natalija M., et al.
Publicado: (2010)

Enantioselective conjugate hydrosilylation of α,β-unsaturated ketones
por: Yang, Huan, et al.
Publicado: (2019)

Cannot write session to /tmp/vufind_sessions/sess_20m1rtv64jifvhh6mu2htcdua7