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Structure confirmation and thermal kinetics of the inclusion of cis-jasmone in β-cyclodextrin

In this study, inclusion complex of cis-jasmone in β-CD (β-CD-CJ) was synthesized to improve cis-jasmone stability. The structure and thermal kinetics of the inclusion complex was investigated by Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TG) and differential scannin...

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Detalles Bibliográficos
Autores principales: Ai, Lvye, Hu, Jingyan, Ji, Xiaoming, Zhao, Huaxin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9070386/
https://www.ncbi.nlm.nih.gov/pubmed/35531039
http://dx.doi.org/10.1039/c9ra03343b
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author Ai, Lvye
Hu, Jingyan
Ji, Xiaoming
Zhao, Huaxin
author_facet Ai, Lvye
Hu, Jingyan
Ji, Xiaoming
Zhao, Huaxin
author_sort Ai, Lvye
collection PubMed
description In this study, inclusion complex of cis-jasmone in β-CD (β-CD-CJ) was synthesized to improve cis-jasmone stability. The structure and thermal kinetics of the inclusion complex was investigated by Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TG) and differential scanning calorimetry (DSC). DSC studies showed that the stability of cis-jasmone after β-cyclodextrin encapsulation was improved. The dissociation kinetics of β-CD-CJ at different heating rates was studied by TG, and the activation energy E of β-CD-CJ thermal decomposition kinetic parameters was defined by Flynn–Wall–Ozawa method. The results showed that the average activation energy E was 121.16 kJ mol(−1).
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spelling pubmed-90703862022-05-05 Structure confirmation and thermal kinetics of the inclusion of cis-jasmone in β-cyclodextrin Ai, Lvye Hu, Jingyan Ji, Xiaoming Zhao, Huaxin RSC Adv Chemistry In this study, inclusion complex of cis-jasmone in β-CD (β-CD-CJ) was synthesized to improve cis-jasmone stability. The structure and thermal kinetics of the inclusion complex was investigated by Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TG) and differential scanning calorimetry (DSC). DSC studies showed that the stability of cis-jasmone after β-cyclodextrin encapsulation was improved. The dissociation kinetics of β-CD-CJ at different heating rates was studied by TG, and the activation energy E of β-CD-CJ thermal decomposition kinetic parameters was defined by Flynn–Wall–Ozawa method. The results showed that the average activation energy E was 121.16 kJ mol(−1). The Royal Society of Chemistry 2019-08-21 /pmc/articles/PMC9070386/ /pubmed/35531039 http://dx.doi.org/10.1039/c9ra03343b Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Ai, Lvye
Hu, Jingyan
Ji, Xiaoming
Zhao, Huaxin
Structure confirmation and thermal kinetics of the inclusion of cis-jasmone in β-cyclodextrin
title Structure confirmation and thermal kinetics of the inclusion of cis-jasmone in β-cyclodextrin
title_full Structure confirmation and thermal kinetics of the inclusion of cis-jasmone in β-cyclodextrin
title_fullStr Structure confirmation and thermal kinetics of the inclusion of cis-jasmone in β-cyclodextrin
title_full_unstemmed Structure confirmation and thermal kinetics of the inclusion of cis-jasmone in β-cyclodextrin
title_short Structure confirmation and thermal kinetics of the inclusion of cis-jasmone in β-cyclodextrin
title_sort structure confirmation and thermal kinetics of the inclusion of cis-jasmone in β-cyclodextrin
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9070386/
https://www.ncbi.nlm.nih.gov/pubmed/35531039
http://dx.doi.org/10.1039/c9ra03343b
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