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Functionalized polycarbonates via triphenylborane catalyzed polymerization-hydrosilylation
Triphenylborane catalyzes the copolymerization and terpolymerization of epoxides and CO(2) to yield polycarbonates with excellent dispersity. Via assisted tandem catalysis, these materials could be hydrosilylated in a one-pot fashion yielding modified polymeric materials. Using only a few reagents,...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9070434/ https://www.ncbi.nlm.nih.gov/pubmed/35528568 http://dx.doi.org/10.1039/c9ra05947d |
| Sumario: | Triphenylborane catalyzes the copolymerization and terpolymerization of epoxides and CO(2) to yield polycarbonates with excellent dispersity. Via assisted tandem catalysis, these materials could be hydrosilylated in a one-pot fashion yielding modified polymeric materials. Using only a few reagents, materials with glass transition temperatures ranging from 37–110 °C were obtained. |
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