Functionalized polycarbonates via triphenylborane catalyzed polymerization-hydrosilylation

Triphenylborane catalyzes the copolymerization and terpolymerization of epoxides and CO(2) to yield polycarbonates with excellent dispersity. Via assisted tandem catalysis, these materials could be hydrosilylated in a one-pot fashion yielding modified polymeric materials. Using only a few reagents,...

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Detalles Bibliográficos
Autores principales: Andrea, Kori A., Kerton, Francesca M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9070434/
https://www.ncbi.nlm.nih.gov/pubmed/35528568
http://dx.doi.org/10.1039/c9ra05947d
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author Andrea, Kori A.
Kerton, Francesca M.
author_facet Andrea, Kori A.
Kerton, Francesca M.
author_sort Andrea, Kori A.
collection PubMed
description Triphenylborane catalyzes the copolymerization and terpolymerization of epoxides and CO(2) to yield polycarbonates with excellent dispersity. Via assisted tandem catalysis, these materials could be hydrosilylated in a one-pot fashion yielding modified polymeric materials. Using only a few reagents, materials with glass transition temperatures ranging from 37–110 °C were obtained.
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spelling pubmed-90704342022-05-05 Functionalized polycarbonates via triphenylborane catalyzed polymerization-hydrosilylation Andrea, Kori A. Kerton, Francesca M. RSC Adv Chemistry Triphenylborane catalyzes the copolymerization and terpolymerization of epoxides and CO(2) to yield polycarbonates with excellent dispersity. Via assisted tandem catalysis, these materials could be hydrosilylated in a one-pot fashion yielding modified polymeric materials. Using only a few reagents, materials with glass transition temperatures ranging from 37–110 °C were obtained. The Royal Society of Chemistry 2019-08-23 /pmc/articles/PMC9070434/ /pubmed/35528568 http://dx.doi.org/10.1039/c9ra05947d Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/
spellingShingle Chemistry
Andrea, Kori A.
Kerton, Francesca M.
Functionalized polycarbonates via triphenylborane catalyzed polymerization-hydrosilylation
title Functionalized polycarbonates via triphenylborane catalyzed polymerization-hydrosilylation
title_full Functionalized polycarbonates via triphenylborane catalyzed polymerization-hydrosilylation
title_fullStr Functionalized polycarbonates via triphenylborane catalyzed polymerization-hydrosilylation
title_full_unstemmed Functionalized polycarbonates via triphenylborane catalyzed polymerization-hydrosilylation
title_short Functionalized polycarbonates via triphenylborane catalyzed polymerization-hydrosilylation
title_sort functionalized polycarbonates via triphenylborane catalyzed polymerization-hydrosilylation
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9070434/
https://www.ncbi.nlm.nih.gov/pubmed/35528568
http://dx.doi.org/10.1039/c9ra05947d
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AT kertonfrancescam functionalizedpolycarbonatesviatriphenylboranecatalyzedpolymerizationhydrosilylation

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