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Pt/Fe co-loaded mesoporous zeolite beta for CO oxidation with high catalytic activity and water resistance
A series of Pt/Fe co-loaded mesoporous zeolite beta (Pt/Fe–mBeta) catalysts with different Fe contents have been successfully synthesized by an ion exchange and subsequent ethylene glycol reduction method. The catalysts were characterized by XRD, N(2) adsorption–desorption, TEM, SEM, XPS and H(2)-TP...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9070763/ https://www.ncbi.nlm.nih.gov/pubmed/35530448 http://dx.doi.org/10.1039/c9ra04599f |
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author | Li, Qinru Zhou, Xiaoxia Zhao, Wanpeng Peng, Chunlei Wu, Huixia Chen, Hangrong |
author_facet | Li, Qinru Zhou, Xiaoxia Zhao, Wanpeng Peng, Chunlei Wu, Huixia Chen, Hangrong |
author_sort | Li, Qinru |
collection | PubMed |
description | A series of Pt/Fe co-loaded mesoporous zeolite beta (Pt/Fe–mBeta) catalysts with different Fe contents have been successfully synthesized by an ion exchange and subsequent ethylene glycol reduction method. The catalysts were characterized by XRD, N(2) adsorption–desorption, TEM, SEM, XPS and H(2)-TPR. The optimized sample Pt/Fe(3)–mBeta shows high catalytic activity for CO oxidation under dry conditions, and the complete conversion temperature of CO is as low as 90 °C. More importantly, the sample Pt/Fe(3)–mBeta also shows excellent water resistance and good durability, which could meet the practical needs of exhaust purification of diesel vehicles. It is believed that the synergistic effect between varied-valence Pt/Fe species and the mesoporous zeolite support with high surface area and good water resistance jointly contribute to the excellent catalytic performance. |
format | Online Article Text |
id | pubmed-9070763 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2019 |
publisher | The Royal Society of Chemistry |
record_format | MEDLINE/PubMed |
spelling | pubmed-90707632022-05-06 Pt/Fe co-loaded mesoporous zeolite beta for CO oxidation with high catalytic activity and water resistance Li, Qinru Zhou, Xiaoxia Zhao, Wanpeng Peng, Chunlei Wu, Huixia Chen, Hangrong RSC Adv Chemistry A series of Pt/Fe co-loaded mesoporous zeolite beta (Pt/Fe–mBeta) catalysts with different Fe contents have been successfully synthesized by an ion exchange and subsequent ethylene glycol reduction method. The catalysts were characterized by XRD, N(2) adsorption–desorption, TEM, SEM, XPS and H(2)-TPR. The optimized sample Pt/Fe(3)–mBeta shows high catalytic activity for CO oxidation under dry conditions, and the complete conversion temperature of CO is as low as 90 °C. More importantly, the sample Pt/Fe(3)–mBeta also shows excellent water resistance and good durability, which could meet the practical needs of exhaust purification of diesel vehicles. It is believed that the synergistic effect between varied-valence Pt/Fe species and the mesoporous zeolite support with high surface area and good water resistance jointly contribute to the excellent catalytic performance. The Royal Society of Chemistry 2019-09-06 /pmc/articles/PMC9070763/ /pubmed/35530448 http://dx.doi.org/10.1039/c9ra04599f Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/ |
spellingShingle | Chemistry Li, Qinru Zhou, Xiaoxia Zhao, Wanpeng Peng, Chunlei Wu, Huixia Chen, Hangrong Pt/Fe co-loaded mesoporous zeolite beta for CO oxidation with high catalytic activity and water resistance |
title | Pt/Fe co-loaded mesoporous zeolite beta for CO oxidation with high catalytic activity and water resistance |
title_full | Pt/Fe co-loaded mesoporous zeolite beta for CO oxidation with high catalytic activity and water resistance |
title_fullStr | Pt/Fe co-loaded mesoporous zeolite beta for CO oxidation with high catalytic activity and water resistance |
title_full_unstemmed | Pt/Fe co-loaded mesoporous zeolite beta for CO oxidation with high catalytic activity and water resistance |
title_short | Pt/Fe co-loaded mesoporous zeolite beta for CO oxidation with high catalytic activity and water resistance |
title_sort | pt/fe co-loaded mesoporous zeolite beta for co oxidation with high catalytic activity and water resistance |
topic | Chemistry |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9070763/ https://www.ncbi.nlm.nih.gov/pubmed/35530448 http://dx.doi.org/10.1039/c9ra04599f |
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