Diaminophosphinoboranes: effective reagents for phosphinoboration of CO(2)

The monomeric diaminophosphinoboranes readily react with CO(2) under mild conditions to cleanly form products of the general formula [Image: see text] in the absence of a catalyst. The isolated products from the CO(2)-phosphinoboration were fully characterized by NMR spectroscopy, IR spectroscopy, a...

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Detalles Bibliográficos
Autores principales: Szynkiewicz, Natalia, Ordyszewska, Anna, Chojnacki, Jarosław, Grubba, Rafał
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9070769/
https://www.ncbi.nlm.nih.gov/pubmed/35530491
http://dx.doi.org/10.1039/c9ra06638a
Descripción
Sumario:The monomeric diaminophosphinoboranes readily react with CO(2) under mild conditions to cleanly form products of the general formula [Image: see text] in the absence of a catalyst. The isolated products from the CO(2)-phosphinoboration were fully characterized by NMR spectroscopy, IR spectroscopy, and X-ray diffraction. The mechanism of CO(2) phosphinoboration with diaminophosphinoboranes was elucidated by DFT calculations.

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