Diaminophosphinoboranes: effective reagents for phosphinoboration of CO(2)

The monomeric diaminophosphinoboranes readily react with CO(2) under mild conditions to cleanly form products of the general formula [Image: see text] in the absence of a catalyst. The isolated products from the CO(2)-phosphinoboration were fully characterized by NMR spectroscopy, IR spectroscopy, a...

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Autores principales: Szynkiewicz, Natalia, Ordyszewska, Anna, Chojnacki, Jarosław, Grubba, Rafał
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9070769/
https://www.ncbi.nlm.nih.gov/pubmed/35530491
http://dx.doi.org/10.1039/c9ra06638a
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author Szynkiewicz, Natalia
Ordyszewska, Anna
Chojnacki, Jarosław
Grubba, Rafał
author_facet Szynkiewicz, Natalia
Ordyszewska, Anna
Chojnacki, Jarosław
Grubba, Rafał
author_sort Szynkiewicz, Natalia
collection PubMed
description The monomeric diaminophosphinoboranes readily react with CO(2) under mild conditions to cleanly form products of the general formula [Image: see text] in the absence of a catalyst. The isolated products from the CO(2)-phosphinoboration were fully characterized by NMR spectroscopy, IR spectroscopy, and X-ray diffraction. The mechanism of CO(2) phosphinoboration with diaminophosphinoboranes was elucidated by DFT calculations.
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spelling pubmed-90707692022-05-06 Diaminophosphinoboranes: effective reagents for phosphinoboration of CO(2) Szynkiewicz, Natalia Ordyszewska, Anna Chojnacki, Jarosław Grubba, Rafał RSC Adv Chemistry The monomeric diaminophosphinoboranes readily react with CO(2) under mild conditions to cleanly form products of the general formula [Image: see text] in the absence of a catalyst. The isolated products from the CO(2)-phosphinoboration were fully characterized by NMR spectroscopy, IR spectroscopy, and X-ray diffraction. The mechanism of CO(2) phosphinoboration with diaminophosphinoboranes was elucidated by DFT calculations. The Royal Society of Chemistry 2019-09-03 /pmc/articles/PMC9070769/ /pubmed/35530491 http://dx.doi.org/10.1039/c9ra06638a Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Szynkiewicz, Natalia
Ordyszewska, Anna
Chojnacki, Jarosław
Grubba, Rafał
Diaminophosphinoboranes: effective reagents for phosphinoboration of CO(2)
title Diaminophosphinoboranes: effective reagents for phosphinoboration of CO(2)
title_full Diaminophosphinoboranes: effective reagents for phosphinoboration of CO(2)
title_fullStr Diaminophosphinoboranes: effective reagents for phosphinoboration of CO(2)
title_full_unstemmed Diaminophosphinoboranes: effective reagents for phosphinoboration of CO(2)
title_short Diaminophosphinoboranes: effective reagents for phosphinoboration of CO(2)
title_sort diaminophosphinoboranes: effective reagents for phosphinoboration of co(2)
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9070769/
https://www.ncbi.nlm.nih.gov/pubmed/35530491
http://dx.doi.org/10.1039/c9ra06638a
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AT ordyszewskaanna diaminophosphinoboraneseffectivereagentsforphosphinoborationofco2
AT chojnackijarosław diaminophosphinoboraneseffectivereagentsforphosphinoborationofco2
AT grubbarafał diaminophosphinoboraneseffectivereagentsforphosphinoborationofco2

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