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Star-poly(ε-caprolactone) as the stationary phase for capillary gas chromatographic separation

This work presents the separation performance of star-poly(ε-caprolactone) (star-PCL) as the stationary phase for capillary gas chromatography (GC). The statically coated star-PCL column showed a column efficiency of 3345 plates per m and moderate polarity. Importantly, the star-PCL column exhibited...

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Autores principales: Sun, Tao, Jiang, Xingxing, Song, Qianqian, Shuai, Xiaomin, Chen, Yujie, Zhao, Xinyu, Cai, Zhiqiang, Li, Ke, Qiao, Xiaoguang, Hu, Shaoqiang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9071194/
https://www.ncbi.nlm.nih.gov/pubmed/35529637
http://dx.doi.org/10.1039/c9ra05085j
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author Sun, Tao
Jiang, Xingxing
Song, Qianqian
Shuai, Xiaomin
Chen, Yujie
Zhao, Xinyu
Cai, Zhiqiang
Li, Ke
Qiao, Xiaoguang
Hu, Shaoqiang
author_facet Sun, Tao
Jiang, Xingxing
Song, Qianqian
Shuai, Xiaomin
Chen, Yujie
Zhao, Xinyu
Cai, Zhiqiang
Li, Ke
Qiao, Xiaoguang
Hu, Shaoqiang
author_sort Sun, Tao
collection PubMed
description This work presents the separation performance of star-poly(ε-caprolactone) (star-PCL) as the stationary phase for capillary gas chromatography (GC). The statically coated star-PCL column showed a column efficiency of 3345 plates per m and moderate polarity. Importantly, the star-PCL column exhibited high selectivity and resolving capability for more than a dozen mixtures covering a wide-ranging variety of analytes and isomers. Among them, the star-PCL column displayed advantageous resolving capability over the commercial DB-1701 column for aromatic amine isomers such as toluidine, chloroaniline and bromoaniline. Moreover, it was applied for the determination of isomer impurities in real samples, showing good potential in GC applications.
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spelling pubmed-90711942022-05-06 Star-poly(ε-caprolactone) as the stationary phase for capillary gas chromatographic separation Sun, Tao Jiang, Xingxing Song, Qianqian Shuai, Xiaomin Chen, Yujie Zhao, Xinyu Cai, Zhiqiang Li, Ke Qiao, Xiaoguang Hu, Shaoqiang RSC Adv Chemistry This work presents the separation performance of star-poly(ε-caprolactone) (star-PCL) as the stationary phase for capillary gas chromatography (GC). The statically coated star-PCL column showed a column efficiency of 3345 plates per m and moderate polarity. Importantly, the star-PCL column exhibited high selectivity and resolving capability for more than a dozen mixtures covering a wide-ranging variety of analytes and isomers. Among them, the star-PCL column displayed advantageous resolving capability over the commercial DB-1701 column for aromatic amine isomers such as toluidine, chloroaniline and bromoaniline. Moreover, it was applied for the determination of isomer impurities in real samples, showing good potential in GC applications. The Royal Society of Chemistry 2019-09-13 /pmc/articles/PMC9071194/ /pubmed/35529637 http://dx.doi.org/10.1039/c9ra05085j Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Sun, Tao
Jiang, Xingxing
Song, Qianqian
Shuai, Xiaomin
Chen, Yujie
Zhao, Xinyu
Cai, Zhiqiang
Li, Ke
Qiao, Xiaoguang
Hu, Shaoqiang
Star-poly(ε-caprolactone) as the stationary phase for capillary gas chromatographic separation
title Star-poly(ε-caprolactone) as the stationary phase for capillary gas chromatographic separation
title_full Star-poly(ε-caprolactone) as the stationary phase for capillary gas chromatographic separation
title_fullStr Star-poly(ε-caprolactone) as the stationary phase for capillary gas chromatographic separation
title_full_unstemmed Star-poly(ε-caprolactone) as the stationary phase for capillary gas chromatographic separation
title_short Star-poly(ε-caprolactone) as the stationary phase for capillary gas chromatographic separation
title_sort star-poly(ε-caprolactone) as the stationary phase for capillary gas chromatographic separation
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9071194/
https://www.ncbi.nlm.nih.gov/pubmed/35529637
http://dx.doi.org/10.1039/c9ra05085j
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