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Tunable pseudocapacitive contribution by dimension control in nanocrystalline-constructed (Mg(0.2)Co(0.2)Ni(0.2)Cu(0.2)Zn(0.2))O solid solutions to achieve superior lithium-storage properties

Ultrafine crystalline materials have been extensively investigated as high-rate lithium-storage materials due to their shortened charge-transport length and high surface area. The pseudocapacitive effect plays a considerable role in electrochemical lithium storage when the electrochemically active m...

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Detalles Bibliográficos
Autores principales: Chen, Hong, Qiu, Nan, Wu, Baozhen, Yang, Zhaoming, Sun, Sen, Wang, Yuan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9071823/
https://www.ncbi.nlm.nih.gov/pubmed/35528405
http://dx.doi.org/10.1039/c9ra05508h
Descripción
Sumario:Ultrafine crystalline materials have been extensively investigated as high-rate lithium-storage materials due to their shortened charge-transport length and high surface area. The pseudocapacitive effect plays a considerable role in electrochemical lithium storage when the electrochemically active materials approach nanoscale dimensions, but this has received limited attention. Herein, a series of (Mg(0.2)Co(0.2)Ni(0.2)Cu(0.2)Zn(0.2))O electrodes with different particle sizes were prepared and tested. The ultrafine (Mg(0.2)Co(0.2)Ni(0.2)Cu(0.2)Zn(0.2))O nanofilm (3–5 nm) anodes show a remarkable rate capability, delivering high specific charge and discharge capacities of 829, 698, 602, 498 and 408 mA h g(−1) at 100, 200, 500, 1000 and 2000 mA g(−1), respectively, and a dominant pseudocapacitive contribution as high as 90.2% toward lithium storage was revealed by electrochemical analysis at a high scanning rate of 1.0 mV s(−1). This work offers an approach to tune the lithium-storage properties of (Mg(0.2)Co(0.2)Ni(0.2)Cu(0.2)Zn(0.2))O by size control and gives insights into the enhancement of pseudocapacitance-assisted lithium-storage capacity.