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Biorenewable rosin derived benzocyclobutene resin: a thermosetting material with good hydrophobicity and low dielectric constant
Development of bio-based polymers has been promoted by the growing concerns about the long-term sustainability and negative environmental footprint of petroleum-based polymer materials. A new monomer containing benzocyclobutene and allyl units has been developed by using rosin as the feedstock. The...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9071944/ https://www.ncbi.nlm.nih.gov/pubmed/35531539 http://dx.doi.org/10.1039/c9ra04828f |
Sumario: | Development of bio-based polymers has been promoted by the growing concerns about the long-term sustainability and negative environmental footprint of petroleum-based polymer materials. A new monomer containing benzocyclobutene and allyl units has been developed by using rosin as the feedstock. The structure of the monomer was characterized by elemental analysis, MS, FT-IR and NMR spectroscopy. The monomer could be converted to the polymer via thermal ring-opening polymerization which was characterized via FT-IR, thermogravimetric analysis (TGA), atom force microscopy (AFM) and so on. The polymer showed good dielectric properties and hydrophobicity with an average dielectric constant of 2.51 in a range of frequencies from 0.1 to 18 MHz and a water contact angle of 106°. In addition, the polymer with other comprehensive performances exhibited a 5% weight loss temperature of 406 °C, a surface roughness (R(a)) of 0.658 nm in a 5.0 × 5.0 μm(2) area, hardness and Young's modulus of 0.283 and 3.542 GPa, and storage modulus of 11.46 GPa at 30 °C. These data suggest that the polymer may have potential application in electronics and microelectronics. |
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