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Hexanuclear Cu(3)O–3Cu triazole-based units as novel core motifs for high nuclearity copper(ii) frameworks
The asymmetric 3,5-disubstituted 1,2,4-triazole ligand H(2)V (5-amino-3-picolinamido-1,2,4-triazole) by reaction with an excess of Cu(ii) perchlorate (Cu : H(2)V being 12 : 1) has produced a novel hexanuclear {Cu(6)(μ(3)-O/H)(HV/V)(3)} fragment, with one triangular Cu(3)(μ(3)-O/H) group connected to...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9071962/ https://www.ncbi.nlm.nih.gov/pubmed/35528438 http://dx.doi.org/10.1039/c9ra05922a |