Electrochemical synthesis of copper(i) acetylides via simultaneous copper ion and catalytic base electrogeneration for use in click chemistry

We report an efficient and sustainable electrochemical synthesis of copper(i) acetylides using simultaneous copper oxidation and Hofmann elimination of quaternary ammonium salts. The electrochemically-generated base was also regenerated electrochemically, making it catalytic. A ‘Click test’ (CuAAC r...

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Detalles Bibliográficos
Autores principales: Seavill, Peter W., Holt, Katherine B., Wilden, Jonathan D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9071997/
https://www.ncbi.nlm.nih.gov/pubmed/35528428
http://dx.doi.org/10.1039/c9ra06782e

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9071997/
https://www.ncbi.nlm.nih.gov/pubmed/35528428
http://dx.doi.org/10.1039/c9ra06782e

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