Acetylene hydrochlorination over boron-doped Pd/HY zeolite catalysts

A novel boron-doped Pd/HY zeolite catalyst for acetylene hydrochlorination was prepared and exhibited an outstanding catalytic performance (the acetylene conversion was maintained at >95% for about 30 h). The boron species can stabilize catalytically active Pd(2+) species and weaken carbon deposi...

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Detalles Bibliográficos
Autores principales: Wang, Lu, Lian, Lizhen, Yan, Haijun, Wang, Feng, Wang, Jide, Yang, Chao, Ma, Lida
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9072090/
https://www.ncbi.nlm.nih.gov/pubmed/35530238
http://dx.doi.org/10.1039/c9ra05576b
Descripción
Sumario:A novel boron-doped Pd/HY zeolite catalyst for acetylene hydrochlorination was prepared and exhibited an outstanding catalytic performance (the acetylene conversion was maintained at >95% for about 30 h). The boron species can stabilize catalytically active Pd(2+) species and weaken carbon deposition and Pd(2+) reduction during the reaction, thus improving the catalytic stability.

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