Ir(iii)-catalyzed thioether directed arene C–H alkenylation

In this study, we demonstrate an Ir(iii)-catalyzed thioether directed alkenylation of arene C–H bonds under mild reaction conditions. The selectivity for mono- or di-alkenylation is controlled by the concentration of alkene and oxidant loading. Various functional groups are tolerated, and moderate t...

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Detalles Bibliográficos
Autores principales: Li, Chen, Chen, Xian, Bao, Rui-Peng, Li, Dong-Li, Zhang, Kun, Wang, Dong-Hui
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9072104/
https://www.ncbi.nlm.nih.gov/pubmed/35530243
http://dx.doi.org/10.1039/c9ra06811b
Descripción
Sumario:In this study, we demonstrate an Ir(iii)-catalyzed thioether directed alkenylation of arene C–H bonds under mild reaction conditions. The selectivity for mono- or di-alkenylation is controlled by the concentration of alkene and oxidant loading. Various functional groups are tolerated, and moderate to good yields of alkenylated products are achieved.

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