Ir(iii)-catalyzed thioether directed arene C–H alkenylation

In this study, we demonstrate an Ir(iii)-catalyzed thioether directed alkenylation of arene C–H bonds under mild reaction conditions. The selectivity for mono- or di-alkenylation is controlled by the concentration of alkene and oxidant loading. Various functional groups are tolerated, and moderate t...

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Detalles Bibliográficos
Autores principales: Li, Chen, Chen, Xian, Bao, Rui-Peng, Li, Dong-Li, Zhang, Kun, Wang, Dong-Hui
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9072104/
https://www.ncbi.nlm.nih.gov/pubmed/35530243
http://dx.doi.org/10.1039/c9ra06811b
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author Li, Chen
Chen, Xian
Bao, Rui-Peng
Li, Dong-Li
Zhang, Kun
Wang, Dong-Hui
author_facet Li, Chen
Chen, Xian
Bao, Rui-Peng
Li, Dong-Li
Zhang, Kun
Wang, Dong-Hui
author_sort Li, Chen
collection PubMed
description In this study, we demonstrate an Ir(iii)-catalyzed thioether directed alkenylation of arene C–H bonds under mild reaction conditions. The selectivity for mono- or di-alkenylation is controlled by the concentration of alkene and oxidant loading. Various functional groups are tolerated, and moderate to good yields of alkenylated products are achieved.
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spelling pubmed-90721042022-05-06 Ir(iii)-catalyzed thioether directed arene C–H alkenylation Li, Chen Chen, Xian Bao, Rui-Peng Li, Dong-Li Zhang, Kun Wang, Dong-Hui RSC Adv Chemistry In this study, we demonstrate an Ir(iii)-catalyzed thioether directed alkenylation of arene C–H bonds under mild reaction conditions. The selectivity for mono- or di-alkenylation is controlled by the concentration of alkene and oxidant loading. Various functional groups are tolerated, and moderate to good yields of alkenylated products are achieved. The Royal Society of Chemistry 2019-09-24 /pmc/articles/PMC9072104/ /pubmed/35530243 http://dx.doi.org/10.1039/c9ra06811b Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Li, Chen
Chen, Xian
Bao, Rui-Peng
Li, Dong-Li
Zhang, Kun
Wang, Dong-Hui
Ir(iii)-catalyzed thioether directed arene C–H alkenylation
title Ir(iii)-catalyzed thioether directed arene C–H alkenylation
title_full Ir(iii)-catalyzed thioether directed arene C–H alkenylation
title_fullStr Ir(iii)-catalyzed thioether directed arene C–H alkenylation
title_full_unstemmed Ir(iii)-catalyzed thioether directed arene C–H alkenylation
title_short Ir(iii)-catalyzed thioether directed arene C–H alkenylation
title_sort ir(iii)-catalyzed thioether directed arene c–h alkenylation
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9072104/
https://www.ncbi.nlm.nih.gov/pubmed/35530243
http://dx.doi.org/10.1039/c9ra06811b
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AT lidongli iriiicatalyzedthioetherdirectedarenechalkenylation
AT zhangkun iriiicatalyzedthioetherdirectedarenechalkenylation
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