SO(2)F(2) mediated cascade dehydrogenative Morita–Baylis–Hillman reaction of the C(sp(3))–H of primary alcohols with the C(sp(2))–H of electron-deficient olefins for the assembly of allylic alcohols

A cascade dehydrogenative Morita–Baylis–Hillman reaction of the C(sp(3))–H of primary alcohols with the C(sp(2))–H of electron-deficient olefins for forming allylic alcohols mediated by SO(2)F(2) was developed. This method provides a mild process for the preparation of allylic alcohol moieties witho...

Descripción completa

Detalles Bibliográficos
Autores principales: Jiang, Ying, Alharbi, Njud S., Sun, Bing, Qin, Hua-Li
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9072135/
https://www.ncbi.nlm.nih.gov/pubmed/35531509
http://dx.doi.org/10.1039/c9ra05346h
Descripción
Sumario:A cascade dehydrogenative Morita–Baylis–Hillman reaction of the C(sp(3))–H of primary alcohols with the C(sp(2))–H of electron-deficient olefins for forming allylic alcohols mediated by SO(2)F(2) was developed. This method provides a mild process for the preparation of allylic alcohol moieties without the requirement of transition metals.

Ejemplares similares