SO(2)F(2) mediated cascade dehydrogenative Morita–Baylis–Hillman reaction of the C(sp(3))–H of primary alcohols with the C(sp(2))–H of electron-deficient olefins for the assembly of allylic alcohols

A cascade dehydrogenative Morita–Baylis–Hillman reaction of the C(sp(3))–H of primary alcohols with the C(sp(2))–H of electron-deficient olefins for forming allylic alcohols mediated by SO(2)F(2) was developed. This method provides a mild process for the preparation of allylic alcohol moieties witho...

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Detalles Bibliográficos
Autores principales: Jiang, Ying, Alharbi, Njud S., Sun, Bing, Qin, Hua-Li
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9072135/
https://www.ncbi.nlm.nih.gov/pubmed/35531509
http://dx.doi.org/10.1039/c9ra05346h
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author Jiang, Ying
Alharbi, Njud S.
Sun, Bing
Qin, Hua-Li
author_facet Jiang, Ying
Alharbi, Njud S.
Sun, Bing
Qin, Hua-Li
author_sort Jiang, Ying
collection PubMed
description A cascade dehydrogenative Morita–Baylis–Hillman reaction of the C(sp(3))–H of primary alcohols with the C(sp(2))–H of electron-deficient olefins for forming allylic alcohols mediated by SO(2)F(2) was developed. This method provides a mild process for the preparation of allylic alcohol moieties without the requirement of transition metals.
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spelling pubmed-90721352022-05-06 SO(2)F(2) mediated cascade dehydrogenative Morita–Baylis–Hillman reaction of the C(sp(3))–H of primary alcohols with the C(sp(2))–H of electron-deficient olefins for the assembly of allylic alcohols Jiang, Ying Alharbi, Njud S. Sun, Bing Qin, Hua-Li RSC Adv Chemistry A cascade dehydrogenative Morita–Baylis–Hillman reaction of the C(sp(3))–H of primary alcohols with the C(sp(2))–H of electron-deficient olefins for forming allylic alcohols mediated by SO(2)F(2) was developed. This method provides a mild process for the preparation of allylic alcohol moieties without the requirement of transition metals. The Royal Society of Chemistry 2019-09-20 /pmc/articles/PMC9072135/ /pubmed/35531509 http://dx.doi.org/10.1039/c9ra05346h Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/
spellingShingle Chemistry
Jiang, Ying
Alharbi, Njud S.
Sun, Bing
Qin, Hua-Li
SO(2)F(2) mediated cascade dehydrogenative Morita–Baylis–Hillman reaction of the C(sp(3))–H of primary alcohols with the C(sp(2))–H of electron-deficient olefins for the assembly of allylic alcohols
title SO(2)F(2) mediated cascade dehydrogenative Morita–Baylis–Hillman reaction of the C(sp(3))–H of primary alcohols with the C(sp(2))–H of electron-deficient olefins for the assembly of allylic alcohols
title_full SO(2)F(2) mediated cascade dehydrogenative Morita–Baylis–Hillman reaction of the C(sp(3))–H of primary alcohols with the C(sp(2))–H of electron-deficient olefins for the assembly of allylic alcohols
title_fullStr SO(2)F(2) mediated cascade dehydrogenative Morita–Baylis–Hillman reaction of the C(sp(3))–H of primary alcohols with the C(sp(2))–H of electron-deficient olefins for the assembly of allylic alcohols
title_full_unstemmed SO(2)F(2) mediated cascade dehydrogenative Morita–Baylis–Hillman reaction of the C(sp(3))–H of primary alcohols with the C(sp(2))–H of electron-deficient olefins for the assembly of allylic alcohols
title_short SO(2)F(2) mediated cascade dehydrogenative Morita–Baylis–Hillman reaction of the C(sp(3))–H of primary alcohols with the C(sp(2))–H of electron-deficient olefins for the assembly of allylic alcohols
title_sort so(2)f(2) mediated cascade dehydrogenative morita–baylis–hillman reaction of the c(sp(3))–h of primary alcohols with the c(sp(2))–h of electron-deficient olefins for the assembly of allylic alcohols
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9072135/
https://www.ncbi.nlm.nih.gov/pubmed/35531509
http://dx.doi.org/10.1039/c9ra05346h
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