5-Bromo-norborn-2-en-7-one derivatives as a carbon monoxide source for palladium catalyzed carbonylation reactions

Norbornenone (5b), obtained from the reaction of 2,5-dimethyl-3,4-diphenylcyclopentadienone dimer (3) with bromomaleic anhydride (4b), provides an excellent base-triggered source of carbon monoxide for palladium-catalysed carbonylation reactions. Aminocarbonylation, ketoamide synthesis, and Suzuki–M...

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Detalles Bibliográficos
Autores principales: Payne, China M., Cho, Kyulee, Larsen, David S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9072167/
https://www.ncbi.nlm.nih.gov/pubmed/35529407
http://dx.doi.org/10.1039/c9ra06594f
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author Payne, China M.
Cho, Kyulee
Larsen, David S.
author_facet Payne, China M.
Cho, Kyulee
Larsen, David S.
author_sort Payne, China M.
collection PubMed
description Norbornenone (5b), obtained from the reaction of 2,5-dimethyl-3,4-diphenylcyclopentadienone dimer (3) with bromomaleic anhydride (4b), provides an excellent base-triggered source of carbon monoxide for palladium-catalysed carbonylation reactions. Aminocarbonylation, ketoamide synthesis, and Suzuki–Miyaura reactions of aryl iodides carried out in a two-chamber reaction vessel gave good to excellent yields of carbonylated products.
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spelling pubmed-90721672022-05-06 5-Bromo-norborn-2-en-7-one derivatives as a carbon monoxide source for palladium catalyzed carbonylation reactions Payne, China M. Cho, Kyulee Larsen, David S. RSC Adv Chemistry Norbornenone (5b), obtained from the reaction of 2,5-dimethyl-3,4-diphenylcyclopentadienone dimer (3) with bromomaleic anhydride (4b), provides an excellent base-triggered source of carbon monoxide for palladium-catalysed carbonylation reactions. Aminocarbonylation, ketoamide synthesis, and Suzuki–Miyaura reactions of aryl iodides carried out in a two-chamber reaction vessel gave good to excellent yields of carbonylated products. The Royal Society of Chemistry 2019-09-30 /pmc/articles/PMC9072167/ /pubmed/35529407 http://dx.doi.org/10.1039/c9ra06594f Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Payne, China M.
Cho, Kyulee
Larsen, David S.
5-Bromo-norborn-2-en-7-one derivatives as a carbon monoxide source for palladium catalyzed carbonylation reactions
title 5-Bromo-norborn-2-en-7-one derivatives as a carbon monoxide source for palladium catalyzed carbonylation reactions
title_full 5-Bromo-norborn-2-en-7-one derivatives as a carbon monoxide source for palladium catalyzed carbonylation reactions
title_fullStr 5-Bromo-norborn-2-en-7-one derivatives as a carbon monoxide source for palladium catalyzed carbonylation reactions
title_full_unstemmed 5-Bromo-norborn-2-en-7-one derivatives as a carbon monoxide source for palladium catalyzed carbonylation reactions
title_short 5-Bromo-norborn-2-en-7-one derivatives as a carbon monoxide source for palladium catalyzed carbonylation reactions
title_sort 5-bromo-norborn-2-en-7-one derivatives as a carbon monoxide source for palladium catalyzed carbonylation reactions
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9072167/
https://www.ncbi.nlm.nih.gov/pubmed/35529407
http://dx.doi.org/10.1039/c9ra06594f
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AT chokyulee 5bromonorborn2en7onederivativesasacarbonmonoxidesourceforpalladiumcatalyzedcarbonylationreactions
AT larsendavids 5bromonorborn2en7onederivativesasacarbonmonoxidesourceforpalladiumcatalyzedcarbonylationreactions

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