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A cobalt(ii) chain based on pymca generated in situ from the hydrolysis of 2-cyanopyrimidine: spin canting and magnetic relaxation
A one-dimensional (1D) coordination polymer, [{Co(2)(pymca)(2)·(H(2)O)(4)}SO(4)·2H(2)O](n) (1) (pymca = 2-carboxypyrimidine), was solvothermally synthesized via the reaction of 2-cyanopyrimidine and Co(SCN)(2). A bidentate pymca ligand was formed in situ by the hydrolysis of 2-cyanopyrimidine. Furth...
| Autores principales: | , , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9072564/ https://www.ncbi.nlm.nih.gov/pubmed/35529373 http://dx.doi.org/10.1039/c9ra05354a |