Efficient production of 5-hydroxymethylfurfural from fructose over CuAPO-5 molecular sieves synthesized using an ionothermal method

A group of CuAPO-5 molecular sieves with trace Cu were successfully synthesized via an ionothermal method and used for fructose dehydration to 5-hydroxymethylfurfural (HMF) in [BMIM]Br ionic liquid. The 0.06-CuAPO-5 sample displayed excellent performance and a HMF yield of 93.8% was obtained, which...

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Autores principales: Huang, Yan, Zhang, Pilan, Hu, Hualei, Hu, Danxin, Yang, Jie, Zhang, Yexin, Chen, Chunlin, Yang, Yong, Zhang, Jian, Wang, Lei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9073099/
https://www.ncbi.nlm.nih.gov/pubmed/35529744
http://dx.doi.org/10.1039/c9ra07217a
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author Huang, Yan
Zhang, Pilan
Hu, Hualei
Hu, Danxin
Yang, Jie
Zhang, Yexin
Chen, Chunlin
Yang, Yong
Zhang, Jian
Wang, Lei
author_facet Huang, Yan
Zhang, Pilan
Hu, Hualei
Hu, Danxin
Yang, Jie
Zhang, Yexin
Chen, Chunlin
Yang, Yong
Zhang, Jian
Wang, Lei
author_sort Huang, Yan
collection PubMed
description A group of CuAPO-5 molecular sieves with trace Cu were successfully synthesized via an ionothermal method and used for fructose dehydration to 5-hydroxymethylfurfural (HMF) in [BMIM]Br ionic liquid. The 0.06-CuAPO-5 sample displayed excellent performance and a HMF yield of 93.8% was obtained, which could be ascribed to the balance between acid strength and mass transfer efficiency. This work demonstrates that the ionothermal synthesized CuAPO-5 molecular sieve was also a good candidate for the efficient production of HMF.
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spelling pubmed-90730992022-05-06 Efficient production of 5-hydroxymethylfurfural from fructose over CuAPO-5 molecular sieves synthesized using an ionothermal method Huang, Yan Zhang, Pilan Hu, Hualei Hu, Danxin Yang, Jie Zhang, Yexin Chen, Chunlin Yang, Yong Zhang, Jian Wang, Lei RSC Adv Chemistry A group of CuAPO-5 molecular sieves with trace Cu were successfully synthesized via an ionothermal method and used for fructose dehydration to 5-hydroxymethylfurfural (HMF) in [BMIM]Br ionic liquid. The 0.06-CuAPO-5 sample displayed excellent performance and a HMF yield of 93.8% was obtained, which could be ascribed to the balance between acid strength and mass transfer efficiency. This work demonstrates that the ionothermal synthesized CuAPO-5 molecular sieve was also a good candidate for the efficient production of HMF. The Royal Society of Chemistry 2019-10-15 /pmc/articles/PMC9073099/ /pubmed/35529744 http://dx.doi.org/10.1039/c9ra07217a Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Huang, Yan
Zhang, Pilan
Hu, Hualei
Hu, Danxin
Yang, Jie
Zhang, Yexin
Chen, Chunlin
Yang, Yong
Zhang, Jian
Wang, Lei
Efficient production of 5-hydroxymethylfurfural from fructose over CuAPO-5 molecular sieves synthesized using an ionothermal method
title Efficient production of 5-hydroxymethylfurfural from fructose over CuAPO-5 molecular sieves synthesized using an ionothermal method
title_full Efficient production of 5-hydroxymethylfurfural from fructose over CuAPO-5 molecular sieves synthesized using an ionothermal method
title_fullStr Efficient production of 5-hydroxymethylfurfural from fructose over CuAPO-5 molecular sieves synthesized using an ionothermal method
title_full_unstemmed Efficient production of 5-hydroxymethylfurfural from fructose over CuAPO-5 molecular sieves synthesized using an ionothermal method
title_short Efficient production of 5-hydroxymethylfurfural from fructose over CuAPO-5 molecular sieves synthesized using an ionothermal method
title_sort efficient production of 5-hydroxymethylfurfural from fructose over cuapo-5 molecular sieves synthesized using an ionothermal method
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9073099/
https://www.ncbi.nlm.nih.gov/pubmed/35529744
http://dx.doi.org/10.1039/c9ra07217a
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