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Tailor-made block copolymers of l-, d- and rac-lactides and ε-caprolactone via one-pot sequential ring opening polymerization by pyridylamidozinc(ii) catalysts

Three-coordinated Zn(ii) complexes bearing sterically encumbered bidentate monoanionic [N,N(−)] pyridylamido ligands efficiently catalyze the ring opening polymerization of lactide (LA) and ε-caprolactone (CL). Owing to the polymerization controlled nature and high rate, precise stereodiblock poly(L...

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Detalles Bibliográficos
Autores principales:	D'Auria, Ilaria, D'Alterio, Massimo Christian, Tedesco, Consiglia, Pellecchia, Claudio
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2019
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9073191/ https://www.ncbi.nlm.nih.gov/pubmed/35529720 http://dx.doi.org/10.1039/c9ra07133d

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