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Silver encapsulated copper salen complex: efficient catalyst for electrocarboxylation of cinnamyl chloride with CO(2)
An active catalyst, [Cu]@Ag composite, was synthesized for the first time and used as a cathode for electrocarboxylation of cinnamyl chloride with CO(2). β,γ-Unsaturated carboxylic acids were obtained with excellent yield and moderate selectivity. Moreover, reasonable yields and selectivities of car...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9073196/ https://www.ncbi.nlm.nih.gov/pubmed/35529726 http://dx.doi.org/10.1039/c9ra05253d |
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| author | Wu, La-Xia Zhao, Ying-Guo Guan, Ye-Bin Wang, Hui Lan, Yang-Chun Wang, Huan Lu, Jia-Xing |
| author_facet | Wu, La-Xia Zhao, Ying-Guo Guan, Ye-Bin Wang, Hui Lan, Yang-Chun Wang, Huan Lu, Jia-Xing |
| author_sort | Wu, La-Xia |
| collection | PubMed |
| description | An active catalyst, [Cu]@Ag composite, was synthesized for the first time and used as a cathode for electrocarboxylation of cinnamyl chloride with CO(2). β,γ-Unsaturated carboxylic acids were obtained with excellent yield and moderate selectivity. Moreover, reasonable yields and selectivities of carboxylic acids were also achieved with several allylic halides and aryl halides. |
| format | Online Article Text |
| id | pubmed-9073196 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2019 |
| publisher | The Royal Society of Chemistry |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-90731962022-05-06 Silver encapsulated copper salen complex: efficient catalyst for electrocarboxylation of cinnamyl chloride with CO(2) Wu, La-Xia Zhao, Ying-Guo Guan, Ye-Bin Wang, Hui Lan, Yang-Chun Wang, Huan Lu, Jia-Xing RSC Adv Chemistry An active catalyst, [Cu]@Ag composite, was synthesized for the first time and used as a cathode for electrocarboxylation of cinnamyl chloride with CO(2). β,γ-Unsaturated carboxylic acids were obtained with excellent yield and moderate selectivity. Moreover, reasonable yields and selectivities of carboxylic acids were also achieved with several allylic halides and aryl halides. The Royal Society of Chemistry 2019-10-15 /pmc/articles/PMC9073196/ /pubmed/35529726 http://dx.doi.org/10.1039/c9ra05253d Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/ |
| spellingShingle | Chemistry Wu, La-Xia Zhao, Ying-Guo Guan, Ye-Bin Wang, Hui Lan, Yang-Chun Wang, Huan Lu, Jia-Xing Silver encapsulated copper salen complex: efficient catalyst for electrocarboxylation of cinnamyl chloride with CO(2) |
| title | Silver encapsulated copper salen complex: efficient catalyst for electrocarboxylation of cinnamyl chloride with CO(2) |
| title_full | Silver encapsulated copper salen complex: efficient catalyst for electrocarboxylation of cinnamyl chloride with CO(2) |
| title_fullStr | Silver encapsulated copper salen complex: efficient catalyst for electrocarboxylation of cinnamyl chloride with CO(2) |
| title_full_unstemmed | Silver encapsulated copper salen complex: efficient catalyst for electrocarboxylation of cinnamyl chloride with CO(2) |
| title_short | Silver encapsulated copper salen complex: efficient catalyst for electrocarboxylation of cinnamyl chloride with CO(2) |
| title_sort | silver encapsulated copper salen complex: efficient catalyst for electrocarboxylation of cinnamyl chloride with co(2) |
| topic | Chemistry |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9073196/ https://www.ncbi.nlm.nih.gov/pubmed/35529726 http://dx.doi.org/10.1039/c9ra05253d |
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