One-step solution synthesis of a two-dimensional semiconducting covalent organometallic nanosheet via the condensation of boronic acid

In this work, a 2D covalent organometallic nanosheet (COMS) was designed and successfully synthesized through the one-step conjunction of a terpyridine–metal–terpyridine (TMT) sandwich coordinate motif with borate ester covalent heterocyclic (B(3)O(3)) linkage via the condensation of boronic acid. T...

Descripción completa

Detalles Bibliográficos
Autores principales: Wang, Qijun, Yan, Jiahao, Xiao, Mingchao, Manoj, Devaraj, Zhong, Cheng, Lv, Qiying, Yang, Lite, Wu, Liangmei, Wang, Zhuoping, Bao, Lihong, Gao, Hongjun, Xiao, Fei, Jiang, Lang, Wang, Shuai
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9073343/
https://www.ncbi.nlm.nih.gov/pubmed/35528421
http://dx.doi.org/10.1039/c9ra05806k
_version_ 1784701263757180928
author Wang, Qijun
Yan, Jiahao
Xiao, Mingchao
Manoj, Devaraj
Zhong, Cheng
Lv, Qiying
Yang, Lite
Wu, Liangmei
Wang, Zhuoping
Bao, Lihong
Gao, Hongjun
Xiao, Fei
Jiang, Lang
Wang, Shuai
author_facet Wang, Qijun
Yan, Jiahao
Xiao, Mingchao
Manoj, Devaraj
Zhong, Cheng
Lv, Qiying
Yang, Lite
Wu, Liangmei
Wang, Zhuoping
Bao, Lihong
Gao, Hongjun
Xiao, Fei
Jiang, Lang
Wang, Shuai
author_sort Wang, Qijun
collection PubMed
description In this work, a 2D covalent organometallic nanosheet (COMS) was designed and successfully synthesized through the one-step conjunction of a terpyridine–metal–terpyridine (TMT) sandwich coordinate motif with borate ester covalent heterocyclic (B(3)O(3)) linkage via the condensation of boronic acid. The obtained 2D COMS with a cobalt coordination center (2D COMS-Co) showed promising p-type semiconducting properties.
format Online
Article
Text
id pubmed-9073343
institution National Center for Biotechnology Information
language English
publishDate 2019
publisher The Royal Society of Chemistry
record_format MEDLINE/PubMed
spelling pubmed-90733432022-05-06 One-step solution synthesis of a two-dimensional semiconducting covalent organometallic nanosheet via the condensation of boronic acid Wang, Qijun Yan, Jiahao Xiao, Mingchao Manoj, Devaraj Zhong, Cheng Lv, Qiying Yang, Lite Wu, Liangmei Wang, Zhuoping Bao, Lihong Gao, Hongjun Xiao, Fei Jiang, Lang Wang, Shuai RSC Adv Chemistry In this work, a 2D covalent organometallic nanosheet (COMS) was designed and successfully synthesized through the one-step conjunction of a terpyridine–metal–terpyridine (TMT) sandwich coordinate motif with borate ester covalent heterocyclic (B(3)O(3)) linkage via the condensation of boronic acid. The obtained 2D COMS with a cobalt coordination center (2D COMS-Co) showed promising p-type semiconducting properties. The Royal Society of Chemistry 2019-09-17 /pmc/articles/PMC9073343/ /pubmed/35528421 http://dx.doi.org/10.1039/c9ra05806k Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Wang, Qijun
Yan, Jiahao
Xiao, Mingchao
Manoj, Devaraj
Zhong, Cheng
Lv, Qiying
Yang, Lite
Wu, Liangmei
Wang, Zhuoping
Bao, Lihong
Gao, Hongjun
Xiao, Fei
Jiang, Lang
Wang, Shuai
One-step solution synthesis of a two-dimensional semiconducting covalent organometallic nanosheet via the condensation of boronic acid
title One-step solution synthesis of a two-dimensional semiconducting covalent organometallic nanosheet via the condensation of boronic acid
title_full One-step solution synthesis of a two-dimensional semiconducting covalent organometallic nanosheet via the condensation of boronic acid
title_fullStr One-step solution synthesis of a two-dimensional semiconducting covalent organometallic nanosheet via the condensation of boronic acid
title_full_unstemmed One-step solution synthesis of a two-dimensional semiconducting covalent organometallic nanosheet via the condensation of boronic acid
title_short One-step solution synthesis of a two-dimensional semiconducting covalent organometallic nanosheet via the condensation of boronic acid
title_sort one-step solution synthesis of a two-dimensional semiconducting covalent organometallic nanosheet via the condensation of boronic acid
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9073343/
https://www.ncbi.nlm.nih.gov/pubmed/35528421
http://dx.doi.org/10.1039/c9ra05806k
work_keys_str_mv AT wangqijun onestepsolutionsynthesisofatwodimensionalsemiconductingcovalentorganometallicnanosheetviathecondensationofboronicacid
AT yanjiahao onestepsolutionsynthesisofatwodimensionalsemiconductingcovalentorganometallicnanosheetviathecondensationofboronicacid
AT xiaomingchao onestepsolutionsynthesisofatwodimensionalsemiconductingcovalentorganometallicnanosheetviathecondensationofboronicacid
AT manojdevaraj onestepsolutionsynthesisofatwodimensionalsemiconductingcovalentorganometallicnanosheetviathecondensationofboronicacid
AT zhongcheng onestepsolutionsynthesisofatwodimensionalsemiconductingcovalentorganometallicnanosheetviathecondensationofboronicacid
AT lvqiying onestepsolutionsynthesisofatwodimensionalsemiconductingcovalentorganometallicnanosheetviathecondensationofboronicacid
AT yanglite onestepsolutionsynthesisofatwodimensionalsemiconductingcovalentorganometallicnanosheetviathecondensationofboronicacid
AT wuliangmei onestepsolutionsynthesisofatwodimensionalsemiconductingcovalentorganometallicnanosheetviathecondensationofboronicacid
AT wangzhuoping onestepsolutionsynthesisofatwodimensionalsemiconductingcovalentorganometallicnanosheetviathecondensationofboronicacid
AT baolihong onestepsolutionsynthesisofatwodimensionalsemiconductingcovalentorganometallicnanosheetviathecondensationofboronicacid
AT gaohongjun onestepsolutionsynthesisofatwodimensionalsemiconductingcovalentorganometallicnanosheetviathecondensationofboronicacid
AT xiaofei onestepsolutionsynthesisofatwodimensionalsemiconductingcovalentorganometallicnanosheetviathecondensationofboronicacid
AT jianglang onestepsolutionsynthesisofatwodimensionalsemiconductingcovalentorganometallicnanosheetviathecondensationofboronicacid
AT wangshuai onestepsolutionsynthesisofatwodimensionalsemiconductingcovalentorganometallicnanosheetviathecondensationofboronicacid

Ejemplares similares