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An advanced and efficient Co(3)O(4)/C nanocomposite for the oxygen evolution reaction in alkaline media

The design of efficient nonprecious catalysts for the hydrogen evolution reaction (HER) or the oxygen evolution reaction (OER) is a necessary, but very challenging task to uplift the water-based economy. In this study, we developed a facile approach to produce porous carbon from the dehydration of s...

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Autores principales: Mugheri, Abdul Qayoom, Tahira, Aneela, Aftab, Umair, Abro, Muhammad Ishaq, Mallah, Arfana Begum, Memon, Gulam Zuhra, Khan, Humaira, Abbasi, Mazhar Ali, Halepoto, Imran Ali, Chaudhry, Saleem Raza, Ibupoto, Zafar Hussain
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9073646/
https://www.ncbi.nlm.nih.gov/pubmed/35529970
http://dx.doi.org/10.1039/c9ra07224a
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author Mugheri, Abdul Qayoom
Tahira, Aneela
Aftab, Umair
Abro, Muhammad Ishaq
Mallah, Arfana Begum
Memon, Gulam Zuhra
Khan, Humaira
Abbasi, Mazhar Ali
Halepoto, Imran Ali
Chaudhry, Saleem Raza
Ibupoto, Zafar Hussain
author_facet Mugheri, Abdul Qayoom
Tahira, Aneela
Aftab, Umair
Abro, Muhammad Ishaq
Mallah, Arfana Begum
Memon, Gulam Zuhra
Khan, Humaira
Abbasi, Mazhar Ali
Halepoto, Imran Ali
Chaudhry, Saleem Raza
Ibupoto, Zafar Hussain
author_sort Mugheri, Abdul Qayoom
collection PubMed
description The design of efficient nonprecious catalysts for the hydrogen evolution reaction (HER) or the oxygen evolution reaction (OER) is a necessary, but very challenging task to uplift the water-based economy. In this study, we developed a facile approach to produce porous carbon from the dehydration of sucrose and use it for the preparation of nanocomposites with cobalt oxide (Co(3)O(4)). The nanocomposites were studied by the powder X-ray diffraction and scanning electron microscopy techniques, and they exhibited the cubic phase of cobalt oxide and porous structure of carbon. The nanocomposites showed significant OER activity in alkaline media, and the current densities of 10 and 20 mA cm(−2) could be obtained at 1.49 and 1.51 V versus reversible hydrogen electrode (RHE), respectively. The impedance study confirms favorable OER activity on the surface of the prepared nanocomposites. The nanocomposite is cost-effective and can be capitalized in various energy storage technologies.
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spelling pubmed-90736462022-05-06 An advanced and efficient Co(3)O(4)/C nanocomposite for the oxygen evolution reaction in alkaline media Mugheri, Abdul Qayoom Tahira, Aneela Aftab, Umair Abro, Muhammad Ishaq Mallah, Arfana Begum Memon, Gulam Zuhra Khan, Humaira Abbasi, Mazhar Ali Halepoto, Imran Ali Chaudhry, Saleem Raza Ibupoto, Zafar Hussain RSC Adv Chemistry The design of efficient nonprecious catalysts for the hydrogen evolution reaction (HER) or the oxygen evolution reaction (OER) is a necessary, but very challenging task to uplift the water-based economy. In this study, we developed a facile approach to produce porous carbon from the dehydration of sucrose and use it for the preparation of nanocomposites with cobalt oxide (Co(3)O(4)). The nanocomposites were studied by the powder X-ray diffraction and scanning electron microscopy techniques, and they exhibited the cubic phase of cobalt oxide and porous structure of carbon. The nanocomposites showed significant OER activity in alkaline media, and the current densities of 10 and 20 mA cm(−2) could be obtained at 1.49 and 1.51 V versus reversible hydrogen electrode (RHE), respectively. The impedance study confirms favorable OER activity on the surface of the prepared nanocomposites. The nanocomposite is cost-effective and can be capitalized in various energy storage technologies. The Royal Society of Chemistry 2019-10-23 /pmc/articles/PMC9073646/ /pubmed/35529970 http://dx.doi.org/10.1039/c9ra07224a Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/
spellingShingle Chemistry
Mugheri, Abdul Qayoom
Tahira, Aneela
Aftab, Umair
Abro, Muhammad Ishaq
Mallah, Arfana Begum
Memon, Gulam Zuhra
Khan, Humaira
Abbasi, Mazhar Ali
Halepoto, Imran Ali
Chaudhry, Saleem Raza
Ibupoto, Zafar Hussain
An advanced and efficient Co(3)O(4)/C nanocomposite for the oxygen evolution reaction in alkaline media
title An advanced and efficient Co(3)O(4)/C nanocomposite for the oxygen evolution reaction in alkaline media
title_full An advanced and efficient Co(3)O(4)/C nanocomposite for the oxygen evolution reaction in alkaline media
title_fullStr An advanced and efficient Co(3)O(4)/C nanocomposite for the oxygen evolution reaction in alkaline media
title_full_unstemmed An advanced and efficient Co(3)O(4)/C nanocomposite for the oxygen evolution reaction in alkaline media
title_short An advanced and efficient Co(3)O(4)/C nanocomposite for the oxygen evolution reaction in alkaline media
title_sort advanced and efficient co(3)o(4)/c nanocomposite for the oxygen evolution reaction in alkaline media
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9073646/
https://www.ncbi.nlm.nih.gov/pubmed/35529970
http://dx.doi.org/10.1039/c9ra07224a
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