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Polymer network-derived nitrogen/sulphur co-doped three-dimensionally interconnected hierarchically porous carbon for oxygen reduction, lithium-ion battery, and supercapacitor
Rational design and simple synthesis of carbon-based materials with high electrocatalytic activity are essential for their practical applications in electrochemical energy conversion and storage devices. Herein, we report the synthesis of nitrogen, sulfur co-doped three-dimensional interconnected hi...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9075119/ https://www.ncbi.nlm.nih.gov/pubmed/35539037 http://dx.doi.org/10.1039/c9ra07619k |
Sumario: | Rational design and simple synthesis of carbon-based materials with high electrocatalytic activity are essential for their practical applications in electrochemical energy conversion and storage devices. Herein, we report the synthesis of nitrogen, sulfur co-doped three-dimensional interconnected hierarchically porous carbon (NSHPC) by zinc acetate assisted pyrolysis of polymer networks. The thus-synthesized NSHPC has a specific surface area of 1057 cm(2) g(−1) with the coexistence of micro- and meso-pores. As metal-free electrocatalyst, the NSHPC exhibits a promising activity towards oxygen reduction reactions as evidenced by the slightly negative shift of half-wave potential compared with commercial Pt/C catalyst. The assembled lithium ion battery using NSHPC as anode delivers the reversible capacity of 740 and 470 mA h g(−1) at current densities of 2 and 5 A g(−1) without performance decay after 1000 charge–discharge cycles. Moreover, the assembled supercapacitor using NSHPC as electrode has the capacitance of 203 F g(−1) at 1 A g(−1). |
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