Platinum–(phosphinito–phosphinous acid) complexes as bi-talented catalysts for oxidative fragmentation of piperidinols: an entry to primary amines

Platinum–(phosphinito–phosphinous acid) complex catalyzes the oxidative fragmentation of hindered piperidinols according to a hydrogen transfer induced methodology. This catalyst acts successively as both a hydrogen carrier and soft Lewis acid in a one pot – two steps process. This method can be app...

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Autores principales: Membrat, Romain, Vasseur, Alexandre, Moraleda, Delphine, Michaud-Chevallier, Sabine, Martinez, Alexandre, Giordano, Laurent, Nuel, Didier
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9075910/
https://www.ncbi.nlm.nih.gov/pubmed/35541801
http://dx.doi.org/10.1039/c9ra08709e
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author Membrat, Romain
Vasseur, Alexandre
Moraleda, Delphine
Michaud-Chevallier, Sabine
Martinez, Alexandre
Giordano, Laurent
Nuel, Didier
author_facet Membrat, Romain
Vasseur, Alexandre
Moraleda, Delphine
Michaud-Chevallier, Sabine
Martinez, Alexandre
Giordano, Laurent
Nuel, Didier
author_sort Membrat, Romain
collection PubMed
description Platinum–(phosphinito–phosphinous acid) complex catalyzes the oxidative fragmentation of hindered piperidinols according to a hydrogen transfer induced methodology. This catalyst acts successively as both a hydrogen carrier and soft Lewis acid in a one pot – two steps process. This method can be applied to the synthesis of a wide variety of primary amines in a pure form by a simple acid–base extraction without further purification.
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spelling pubmed-90759102022-05-09 Platinum–(phosphinito–phosphinous acid) complexes as bi-talented catalysts for oxidative fragmentation of piperidinols: an entry to primary amines Membrat, Romain Vasseur, Alexandre Moraleda, Delphine Michaud-Chevallier, Sabine Martinez, Alexandre Giordano, Laurent Nuel, Didier RSC Adv Chemistry Platinum–(phosphinito–phosphinous acid) complex catalyzes the oxidative fragmentation of hindered piperidinols according to a hydrogen transfer induced methodology. This catalyst acts successively as both a hydrogen carrier and soft Lewis acid in a one pot – two steps process. This method can be applied to the synthesis of a wide variety of primary amines in a pure form by a simple acid–base extraction without further purification. The Royal Society of Chemistry 2019-11-20 /pmc/articles/PMC9075910/ /pubmed/35541801 http://dx.doi.org/10.1039/c9ra08709e Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Membrat, Romain
Vasseur, Alexandre
Moraleda, Delphine
Michaud-Chevallier, Sabine
Martinez, Alexandre
Giordano, Laurent
Nuel, Didier
Platinum–(phosphinito–phosphinous acid) complexes as bi-talented catalysts for oxidative fragmentation of piperidinols: an entry to primary amines
title Platinum–(phosphinito–phosphinous acid) complexes as bi-talented catalysts for oxidative fragmentation of piperidinols: an entry to primary amines
title_full Platinum–(phosphinito–phosphinous acid) complexes as bi-talented catalysts for oxidative fragmentation of piperidinols: an entry to primary amines
title_fullStr Platinum–(phosphinito–phosphinous acid) complexes as bi-talented catalysts for oxidative fragmentation of piperidinols: an entry to primary amines
title_full_unstemmed Platinum–(phosphinito–phosphinous acid) complexes as bi-talented catalysts for oxidative fragmentation of piperidinols: an entry to primary amines
title_short Platinum–(phosphinito–phosphinous acid) complexes as bi-talented catalysts for oxidative fragmentation of piperidinols: an entry to primary amines
title_sort platinum–(phosphinito–phosphinous acid) complexes as bi-talented catalysts for oxidative fragmentation of piperidinols: an entry to primary amines
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9075910/
https://www.ncbi.nlm.nih.gov/pubmed/35541801
http://dx.doi.org/10.1039/c9ra08709e
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