Selective detection of trinitrophenol by a Cd(ii)-based coordination compound

A Cd(ii)-based coordination compound, [CdI(2)(4-nvp)(2)] (1), has been synthesized using CdI(2) and monodentate N-donor ligand 4-(1-naphthylvinyl)pyridine (4-nvp). The solid-state supramolecular architecture has been characterized by X-ray crystallography. An acute thermal stability and excellent le...

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Detalles Bibliográficos
Autores principales: Dutta, Basudeb, Purkait, Rakesh, Bhunia, Suprava, Khan, Samim, Sinha, Chittaranjan, Mir, Mohammad Hedayetullah
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9075976/
https://www.ncbi.nlm.nih.gov/pubmed/35540192
http://dx.doi.org/10.1039/c9ra08614e
Descripción
Sumario:A Cd(ii)-based coordination compound, [CdI(2)(4-nvp)(2)] (1), has been synthesized using CdI(2) and monodentate N-donor ligand 4-(1-naphthylvinyl)pyridine (4-nvp). The solid-state supramolecular architecture has been characterized by X-ray crystallography. An acute thermal stability and excellent level of phase purity tempted us to use it for material applications. Interestingly, compound 1 exhibits a high selectivity towards trinitrophenol (TNP) in the presence of other nitroaromatics. Therefore, this material may be used for anti-terrorist activities in the detection of explosive materials as well as in the recognition of TNP in analytical laboratories.

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