Selective detection of trinitrophenol by a Cd(ii)-based coordination compound

A Cd(ii)-based coordination compound, [CdI(2)(4-nvp)(2)] (1), has been synthesized using CdI(2) and monodentate N-donor ligand 4-(1-naphthylvinyl)pyridine (4-nvp). The solid-state supramolecular architecture has been characterized by X-ray crystallography. An acute thermal stability and excellent le...

Descripción completa

Detalles Bibliográficos
Autores principales: Dutta, Basudeb, Purkait, Rakesh, Bhunia, Suprava, Khan, Samim, Sinha, Chittaranjan, Mir, Mohammad Hedayetullah
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9075976/
https://www.ncbi.nlm.nih.gov/pubmed/35540192
http://dx.doi.org/10.1039/c9ra08614e
_version_ 1784701807418671104
author Dutta, Basudeb
Purkait, Rakesh
Bhunia, Suprava
Khan, Samim
Sinha, Chittaranjan
Mir, Mohammad Hedayetullah
author_facet Dutta, Basudeb
Purkait, Rakesh
Bhunia, Suprava
Khan, Samim
Sinha, Chittaranjan
Mir, Mohammad Hedayetullah
author_sort Dutta, Basudeb
collection PubMed
description A Cd(ii)-based coordination compound, [CdI(2)(4-nvp)(2)] (1), has been synthesized using CdI(2) and monodentate N-donor ligand 4-(1-naphthylvinyl)pyridine (4-nvp). The solid-state supramolecular architecture has been characterized by X-ray crystallography. An acute thermal stability and excellent level of phase purity tempted us to use it for material applications. Interestingly, compound 1 exhibits a high selectivity towards trinitrophenol (TNP) in the presence of other nitroaromatics. Therefore, this material may be used for anti-terrorist activities in the detection of explosive materials as well as in the recognition of TNP in analytical laboratories.
format Online
Article
Text
id pubmed-9075976
institution National Center for Biotechnology Information
language English
publishDate 2019
publisher The Royal Society of Chemistry
record_format MEDLINE/PubMed
spelling pubmed-90759762022-05-09 Selective detection of trinitrophenol by a Cd(ii)-based coordination compound Dutta, Basudeb Purkait, Rakesh Bhunia, Suprava Khan, Samim Sinha, Chittaranjan Mir, Mohammad Hedayetullah RSC Adv Chemistry A Cd(ii)-based coordination compound, [CdI(2)(4-nvp)(2)] (1), has been synthesized using CdI(2) and monodentate N-donor ligand 4-(1-naphthylvinyl)pyridine (4-nvp). The solid-state supramolecular architecture has been characterized by X-ray crystallography. An acute thermal stability and excellent level of phase purity tempted us to use it for material applications. Interestingly, compound 1 exhibits a high selectivity towards trinitrophenol (TNP) in the presence of other nitroaromatics. Therefore, this material may be used for anti-terrorist activities in the detection of explosive materials as well as in the recognition of TNP in analytical laboratories. The Royal Society of Chemistry 2019-11-26 /pmc/articles/PMC9075976/ /pubmed/35540192 http://dx.doi.org/10.1039/c9ra08614e Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/
spellingShingle Chemistry
Dutta, Basudeb
Purkait, Rakesh
Bhunia, Suprava
Khan, Samim
Sinha, Chittaranjan
Mir, Mohammad Hedayetullah
Selective detection of trinitrophenol by a Cd(ii)-based coordination compound
title Selective detection of trinitrophenol by a Cd(ii)-based coordination compound
title_full Selective detection of trinitrophenol by a Cd(ii)-based coordination compound
title_fullStr Selective detection of trinitrophenol by a Cd(ii)-based coordination compound
title_full_unstemmed Selective detection of trinitrophenol by a Cd(ii)-based coordination compound
title_short Selective detection of trinitrophenol by a Cd(ii)-based coordination compound
title_sort selective detection of trinitrophenol by a cd(ii)-based coordination compound
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9075976/
https://www.ncbi.nlm.nih.gov/pubmed/35540192
http://dx.doi.org/10.1039/c9ra08614e
work_keys_str_mv AT duttabasudeb selectivedetectionoftrinitrophenolbyacdiibasedcoordinationcompound
AT purkaitrakesh selectivedetectionoftrinitrophenolbyacdiibasedcoordinationcompound
AT bhuniasuprava selectivedetectionoftrinitrophenolbyacdiibasedcoordinationcompound
AT khansamim selectivedetectionoftrinitrophenolbyacdiibasedcoordinationcompound
AT sinhachittaranjan selectivedetectionoftrinitrophenolbyacdiibasedcoordinationcompound
AT mirmohammadhedayetullah selectivedetectionoftrinitrophenolbyacdiibasedcoordinationcompound

Ejemplares similares