Highly selective synthesis of 2,5-bis(aminomethyl)furan via catalytic amination of 5-(hydroxymethyl)furfural with NH(3) over a bifunctional catalyst

The development of facile protocols for the selective synthesis of biomass-derived diamine is a highly desirable pursuit in the field of heterogeneous catalysis. Herein, a simple and highly efficient bi-functional CuNiAlO(x) catalyst was developed for the one pot transformation of 5-(hydroxymethyl)f...

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Autores principales: Yuan, Hangkong, Kusema, Bright T., Yan, Zhen, Streiff, Stéphane, Shi, Feng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9076022/
https://www.ncbi.nlm.nih.gov/pubmed/35540204
http://dx.doi.org/10.1039/c9ra08560b
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author Yuan, Hangkong
Kusema, Bright T.
Yan, Zhen
Streiff, Stéphane
Shi, Feng
author_facet Yuan, Hangkong
Kusema, Bright T.
Yan, Zhen
Streiff, Stéphane
Shi, Feng
author_sort Yuan, Hangkong
collection PubMed
description The development of facile protocols for the selective synthesis of biomass-derived diamine is a highly desirable pursuit in the field of heterogeneous catalysis. Herein, a simple and highly efficient bi-functional CuNiAlO(x) catalyst was developed for the one pot transformation of 5-(hydroxymethyl)furfural (5-HMF) into 2,5-bis(aminomethyl)furan (BAF) using a two-stage reaction process. Cu(4)Ni(1)Al(4)O(x) was found to be the most effective catalyst for this reaction, affording BAF in 85.9% yield. Our results could promote controllable conversion and utilization of biomass resource.
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spelling pubmed-90760222022-05-09 Highly selective synthesis of 2,5-bis(aminomethyl)furan via catalytic amination of 5-(hydroxymethyl)furfural with NH(3) over a bifunctional catalyst Yuan, Hangkong Kusema, Bright T. Yan, Zhen Streiff, Stéphane Shi, Feng RSC Adv Chemistry The development of facile protocols for the selective synthesis of biomass-derived diamine is a highly desirable pursuit in the field of heterogeneous catalysis. Herein, a simple and highly efficient bi-functional CuNiAlO(x) catalyst was developed for the one pot transformation of 5-(hydroxymethyl)furfural (5-HMF) into 2,5-bis(aminomethyl)furan (BAF) using a two-stage reaction process. Cu(4)Ni(1)Al(4)O(x) was found to be the most effective catalyst for this reaction, affording BAF in 85.9% yield. Our results could promote controllable conversion and utilization of biomass resource. The Royal Society of Chemistry 2019-11-27 /pmc/articles/PMC9076022/ /pubmed/35540204 http://dx.doi.org/10.1039/c9ra08560b Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Yuan, Hangkong
Kusema, Bright T.
Yan, Zhen
Streiff, Stéphane
Shi, Feng
Highly selective synthesis of 2,5-bis(aminomethyl)furan via catalytic amination of 5-(hydroxymethyl)furfural with NH(3) over a bifunctional catalyst
title Highly selective synthesis of 2,5-bis(aminomethyl)furan via catalytic amination of 5-(hydroxymethyl)furfural with NH(3) over a bifunctional catalyst
title_full Highly selective synthesis of 2,5-bis(aminomethyl)furan via catalytic amination of 5-(hydroxymethyl)furfural with NH(3) over a bifunctional catalyst
title_fullStr Highly selective synthesis of 2,5-bis(aminomethyl)furan via catalytic amination of 5-(hydroxymethyl)furfural with NH(3) over a bifunctional catalyst
title_full_unstemmed Highly selective synthesis of 2,5-bis(aminomethyl)furan via catalytic amination of 5-(hydroxymethyl)furfural with NH(3) over a bifunctional catalyst
title_short Highly selective synthesis of 2,5-bis(aminomethyl)furan via catalytic amination of 5-(hydroxymethyl)furfural with NH(3) over a bifunctional catalyst
title_sort highly selective synthesis of 2,5-bis(aminomethyl)furan via catalytic amination of 5-(hydroxymethyl)furfural with nh(3) over a bifunctional catalyst
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9076022/
https://www.ncbi.nlm.nih.gov/pubmed/35540204
http://dx.doi.org/10.1039/c9ra08560b
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